Synthesis and alignment of iron oxide nanoparticles in a regenerated cellulose film

被引：42
作者：
Liu, Shilin
Zhou, Jinping [1 ]
Zhang, Lina
Guan, Jianguo
Wang, Jianbo
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[3] Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China
[4] Wuhan Univ, Ctr Electron Microscopy, Wuhan 430072, Peoples R China
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 24期
关键词：
alignment; cellulose film; iron oxide; nanocomposites; templates;
D O I：
10.1002/marc.200600543
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A polymer-iron oxide nanocomposite film has been successfully synthesized by using a microporous regenerated cellulose film as template and aqueous ferrous chloride a precursor. the nanocomposite film was investigated wit XRD, XPS, SEM, TEM, and VSM. The nanoparticles synthesized in situ were disk-shaped with a mean diameter of approximate to 24 and thickness of 2.5-3.5 nm. For the first time, the nanodisks were well aligned in the cellulose matrix to form an ordered multibilayer structure by the shrinkage of the hybrid film while drying. The nanocomposite film displayed anisotropic magnetic properties as a result of the alignment of magnetic nanodisks. This work provides a novel and facile method for template synthesis of nanoparticles and aligned nanocomposites.
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收藏
页码：2084 / 2089
页数：6
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