A stereoselective synthesis of (E)-α-stannylvinyl sulfones via palladium-catalyzed hydrostannylation of acetylenic sulfones

被引：12

作者：

Cai, Mingzhong ^{[1
]}

Chen, Guiqin ^{[1
]}

Hao, Wenyan ^{[1
]}

Wang, Dong ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330022, Peoples R China

来源：

SYNLETT | 2006年 / 20期

关键词：

hydrostannylation; acetylenic sulfone; palladium; (E)-alpha-stannylvinyl sulfone; stereoselective synthesis;

D O I：

10.1055/s-2006-958432

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed hydrostannylation of acetylenic sulfones with Bu3SnH in benzene at room temperature afforded stereoselectively (E)-alpha-stannylvinyl sulfones in good to high yields.

引用

页码：3492 / 3494

页数：3

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