Nonfullerene Polymer Solar Cell with Large Active Area of 216 cm2 and High Power Conversion Efficiency of 7.7%

被引：33

作者：

Huang, Kuan-Min ^{[1
]}

Lin, Chih-Ming ^{[2
]}

Chen, Szu-Han ^{[3
]}

Li, Cheng-Sian ^{[2
]}

Hu, Chen-Hsuan ^{[3
]}

Zhang, Yu ^{[4
]}

Meng, Hsin-Fei ^{[3
]}

Chang, Chih-Yu ^{[5
]}

Chao, Yu-Chiang ^{[6
]}

Zan, Hsiao-Wen ^{[1
]}

Huo, Lijun ^{[4
]}

Yu, Peichen ^{[1
]}

机构：

[1] Natl Chiao Tung Univ, Coll Elect & Comp Engn, Dept Photon, Hsinchu 300, Taiwan

[2] Natl Tsing Hua Univ, Inst Elect Engn, Hsinchu 300, Taiwan

[3] Natl Chiao Tung Univ, Inst Phys, Hsinchu 300, Taiwan

[4] Beihang Univ, Sch Chem & Environm, Heeger Beijing Res & Dev Ctr, Beijing 100191, Peoples R China

[5] Taipei Med Univ, Grad Inst Nanomed & Med Engn, Taipei 110, Taiwan

[6] Natl Taiwan Normal Univ, Dept Phys, Taipei 106, Taiwan

来源：

SOLAR RRL | 2019年 / 3卷 / 08期

关键词：

large-area; nonfullerene; polymer solar cells; solution-processable interfacial layer; stability; ORGANIC PHOTOVOLTAIC MODULES; NON-FULLERENE ACCEPTOR; LAYER; PERFORMANCE; ELECTRODES; STABILITY;

D O I：

10.1002/solr.201900071

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A polymer solar cell involving a nonfullerene acceptor is made by blade coating. In the ternary bulk-heterojunction layer, the donor is poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophene))-co-(1,3-di(5-thiophene-2-yl)- 5,7-bis(2-ethylhexyl)benzo[1,2-c:4,5-c']dithiophene-4,8-dione)] (PBDB-T) and the acceptor is a mixture of 3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3'-d']-s-indaceno[1,2-b:5,6-b']dithiophene) (ITIC) and [6,6]-phenyl C-71-butyric acid methyl ester (PC71BM). The device structure is an indium tin oxide (ITO)-coated glass substrate/PEDOT:PSS/ternary active layer/interfacial layer/Al. For a small active area of 0.04 cm(2), the best power conversion efficiency is 9.8% with the LiF interfacial layer. For a large active area of 216 cm(2), the best efficiency is 7.7% with the ZrOx interfacial layer. After annealing at 85 degrees C for 30 days, the large-area device keeps 75% of the initial efficiency. The efficiency of 4.9% is achieved for a large-area semi-transparent device.

引用

页数：13

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