Tetra-μ-acetato-κ8O:O′-bis{[2-(m-tolylamino)pyridine-κN]copper(II)}

被引:2
作者
Fairuz, Zainal Abidin [1 ]
Aiyub, Zaharah [1 ]
Abdullah, Zanariah [1 ]
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
CRYSTAL-STRUCTURE;
D O I
10.1107/S1600536809050041
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, [Cu-2(C2H3O2)(4)(C12H12N2)(2)], the binuclear molecule lies about a center of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. The pyridine ring is twisted with respect to the benzene ring at a dihedral angle of 45.68 (16)degrees. Intramolecular N-H center dot center dot center dot O hydrogen bonding is present between the imino and carboxy groups.
引用
收藏
页码:M1690 / U1623
页数:9
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