Synthesis and characterization of chemically stable sulfonated copoly(triazole imide)s with high proton conductivity

The synthesis and characterization of a series of new sulfonated copoly(triazole imide)s (PTPQSH-XX) are reported in this work. The PTPQSH-XX with different degree of sulfonation (DS) were prepared by click polymerization of equimolar amounts of a diimide-based dialkyne monomer, namely bis-N,N '-(prop-2-ynyl)pyromellitic diimide (TP) and a mixture of two different diazide monomers (one sulfonated, 4,4-bis[3 '-trifluoromethyl-4 '{4-azidobenzoxy} benzyl] biphenyl, and another nonsulfonated, 4,4 '-diazido-2,2 '-stilbene disulfonic acid disodium salt [SAZ]), in different molar ratios. The copolymers showed high inherent viscosity (1.12-1.28 dL/g) in n-methyl pyrrolidone (NMP) indicating the formation of high molar masses. Freestanding membranes were prepared from these copolymers by solution casting method. DS of the copolymers was determined from H-1 NMR signal intensities, and the values were in good agreement with the quantity of SAZ monomer used in polymer feed, indicating the successful incorporation of the sulfonated monomer. The copolymers exhibited high thermal and mechanical stabilities. The PTPQSH-80 membrane showed proton conductivity as high as 178 mS/cm at 90 degrees C with good oxidative and hydrolytic stability. Cross-sectional transmission electron microscope micrographs of the membranes indicated phase segregated morphology along with interconnected hydrophilic domains with dimension in the range 15-150 nm. POLYM. ENG. SCI., 2019. (c) 2019 Society of Plastics Engineers