Synthesis of biomass-derived feedstocks for the polymers and fuels industries from 5-(hydroxymethyl)furfural (HMF) and acetone

被引：63
作者：
Chang, Hochan [1 ]
Motagamwala, Ali Hussain [1 ,2 ]
Huber, George W. [1 ]
Dumesic, James A. [1 ,2 ]
机构：
[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA
[2] Univ Wisconsin, DOE Great Lakes Bioenerg Res Ctr, 1552 Univ Ave, Madison, WI 53726 USA
来源：
GREEN CHEMISTRY | 2019年 / 21卷 / 20期
关键词：
HYDROXYMETHYLFURFURAL HMF; ALDOL-CONDENSATION; LIQUID ALKANES; RANGE ALKANES; ACID; DIESEL; 2-METHYLFURAN; CATALYSTS; CONVERSION; RESIN;
D O I：
10.1039/c9gc01859j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We show that 5-(hydroxymethyl) furfural (HMF) and acetone can be selectively converted into a range of biomass-derived high molecular weight chemicals in high yield (>90%). HMF was condensed with acetone and purified to produce HMF-Acetone-HMF dimer (HAH). We then selectively synthesized various compounds from HAH by the sequential catalytic reaction pathway of hydrogenation, ringopening, and hydrodeoxygenation. These synthesized HMF-derived chemicals were characterized by 1D and 2D NMR spectra and high resolution mass spectrometry (HRMS). The HMF-derived molecules described in this paper can be feedstocks for the polymer, pigment, and petroleum industries.
引用
收藏
页码：5532 / 5540
页数：9
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