Synthesis of biomass-derived feedstocks for the polymers and fuels industries from 5-(hydroxymethyl)furfural (HMF) and acetone

被引：66

作者：

Chang, Hochan ^{[1
]}

Motagamwala, Ali Hussain ^{[1
,2
]}

Huber, George W. ^{[1
]}

Dumesic, James A. ^{[1
,2
]}

机构：

[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA

[2] Univ Wisconsin, DOE Great Lakes Bioenerg Res Ctr, 1552 Univ Ave, Madison, WI 53726 USA

来源：

GREEN CHEMISTRY | 2019年 / 21卷 / 20期

关键词：

HYDROXYMETHYLFURFURAL HMF; ALDOL-CONDENSATION; LIQUID ALKANES; RANGE ALKANES; ACID; DIESEL; 2-METHYLFURAN; CATALYSTS; CONVERSION; RESIN;

D O I：

10.1039/c9gc01859j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that 5-(hydroxymethyl) furfural (HMF) and acetone can be selectively converted into a range of biomass-derived high molecular weight chemicals in high yield (>90%). HMF was condensed with acetone and purified to produce HMF-Acetone-HMF dimer (HAH). We then selectively synthesized various compounds from HAH by the sequential catalytic reaction pathway of hydrogenation, ringopening, and hydrodeoxygenation. These synthesized HMF-derived chemicals were characterized by 1D and 2D NMR spectra and high resolution mass spectrometry (HRMS). The HMF-derived molecules described in this paper can be feedstocks for the polymer, pigment, and petroleum industries.

引用

页码：5532 / 5540

页数：9

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