Dichlorido[N′-(3,5-dichloro-2-hydroxybenzylidene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κ2N,N′)cobalt(II) methanol monosolvate

被引:1
作者
Wang, Yuan
Liu, Zheng [1 ]
Liu, Baoyu
机构
[1] Guilin Univ Technol, Minist Educ, Dept Mat & Chem Engn, Key Lab Nonferrous Met Mat & Proc Technol, Guilin 541004, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
COMPLEXES;
D O I
10.1107/S1600536809047680
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [CoCl2(C13H9Cl2N3O2)(2)(C12H8N2)]center dot CH3OH, the Co-II atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N '-(3,5-dichloro2- hydroxybenzylidene)pyridine-4-carbohydrazide (H2L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acylhydrazone groups are not involved into the coordination of the metal ion. In the crystal packing an extended three-dimensional network formed by N-H center dot center dot center dot Cl, N-H center dot center dot center dot O, O-H center dot center dot center dot N, O-H center dot center dot center dot N and O-H center dot center dot center dot Cl hydrogen bonds is observed.
引用
收藏
页码:M1594 / U879
页数:14
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