A novel cross-linked nano-coating for carbon dioxide capture

被引:92
作者
Fu, Qiang [1 ,2 ]
Kim, Jinguk [1 ,2 ]
Gurr, Paul A. [1 ,2 ]
Scofield, Joel M. P. [1 ,2 ]
Kentish, Sandra E. [1 ,2 ]
Qiao, Greg G. [1 ,2 ]
机构
[1] Univ Melbourne, Cooperat Res Ctr Greenhouse Gas Technol, Parkville, Vic 3010, Australia
[2] Univ Melbourne, Dept Chem & Biomol Engn, Polymer Sci Grp, Parkville, Vic 3010, Australia
基金
澳大利亚研究理事会;
关键词
TRANSFER RADICAL POLYMERIZATION; GAS SEPARATION MEMBRANES; FILM COMPOSITE MEMBRANES; GRAPHENE OXIDE MEMBRANES; HOLLOW-FIBER MEMBRANES; CO2; SEPARATION; TRANSPORT; PERFORMANCE; POLYMERS; PERMEATION;
D O I
10.1039/c5ee02433a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultra-thin (similar to 100 nm) films with uniform thicknesses can facilitate high CO2 permeation and are of potential technological significance for CO2 capture. Among many approaches for obtaining such materials, the recently developed continuous assembly of polymers (CAP) technology provides a robust process, allowing for the production of defect-free, cross-linked and surface-confined thin films with nanometer scale precision. Through utilization of this nanotechnology, we have constructed composite membranes containing cross-linked ultra-thin surface films. The membrane materials formed exhibited significantly high permeances as well as excellent gas separation selectivity.
引用
收藏
页码:434 / 440
页数:7
相关论文
共 40 条
[21]   High-Flux SAPO-34 Membrane for CO2/N2 Separation [J].
Li, Shiguang ;
Fan, Chinbay Q. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (09) :4399-4404
[22]   Transport and structural characteristics of crosslinked poly(ethylene oxide) rubbers [J].
Lin, HQ ;
Van Wagner, E ;
Swinnea, JS ;
Freeman, BD ;
Pas, SJ ;
Hill, AJ ;
Kalakkunnath, S ;
Kalika, DS .
JOURNAL OF MEMBRANE SCIENCE, 2006, 276 (1-2) :145-161
[23]   The effect of cross-linking on gas permeability in cross-linked poly(ethylene glycol diacrylate) [J].
Lin, HQ ;
Kai, T ;
Freeman, BD ;
Kalakkunnath, S ;
Kalika, DS .
MACROMOLECULES, 2005, 38 (20) :8381-8393
[24]  
Matyjaszewski K, 2009, NAT CHEM, V1, P276, DOI [10.1038/NCHEM.257, 10.1038/nchem.257]
[25]   Power plant post-combustion carbon dioxide capture: An opportunity for membranes [J].
Merkel, Tim C. ;
Lin, Haiqing ;
Wei, Xiaotong ;
Baker, Richard .
JOURNAL OF MEMBRANE SCIENCE, 2010, 359 (1-2) :126-139
[26]   ATRP-mediated continuous assembly of polymers for the preparation of nanoscale films [J].
Mertz, Damien ;
Ochs, Christopher J. ;
Zhu, Zhiyuan ;
Lee, Lillian ;
Guntari, Stefanie N. ;
Such, Georgina K. ;
Goh, Tor Kit ;
Connal, Luke A. ;
Blencowe, Anton ;
Qiao, Greg G. ;
Caruso, Frank .
CHEMICAL COMMUNICATIONS, 2011, 47 (47) :12601-12603
[27]   Continuous assembly of polymers via solid phase reactions [J].
Nam, Eunhyung ;
Kim, Jinguk ;
Guntari, Stefanie N. ;
Seyler, Helga ;
Fu, Qiang ;
Wong, Edgar H. H. ;
Blencowe, Anton ;
Jones, David J. ;
Caruso, Frank ;
Qiao, Greg G. .
CHEMICAL SCIENCE, 2014, 5 (09) :3374-3380
[28]   Fabrication and characterization of nanoporous carbon/silica membranes [J].
Park, HB ;
Lee, YM .
ADVANCED MATERIALS, 2005, 17 (04) :477-+
[29]   Polymers with cavities tuned for fast selective transport of small molecules and ions [J].
Park, Ho Bum ;
Jung, Chul Ho ;
Lee, Young Moo ;
Hill, Anita J. ;
Pas, Steven J. ;
Mudie, Stephen T. ;
Van Wagner, Elizabeth ;
Freeman, Benny D. ;
Cookson, David J. .
SCIENCE, 2007, 318 (5848) :254-258
[30]   Polymeric CO2/N2 gas separation membranes for the capture of carbon dioxide from power plant flue gases [J].
Powell, Clem E. ;
Qiao, Greg G. .
JOURNAL OF MEMBRANE SCIENCE, 2006, 279 (1-2) :1-49