Fullerenes as tilings of surfaces

被引:82
作者
Deza, M
Fowler, PW
Rassat, A
Rogers, KM
机构
[1] Ecole Normale Super, Lab Informat, F-75230 Paris, France
[2] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
[3] Ecole Normale Super, Dept Chem, F-75005 Paris, France
来源
JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES | 2000年 / 40卷 / 03期
关键词
D O I
10.1021/ci990066h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
If a fullerene is defined as a finite trivalent graph made up solely of pentagons and hexagons, embedding in only four surfaces is possible: the sphere, torus, Klein bottle, and projective (elliptic) plane. The usual spherical fullerenes have 12 pentagons; elliptic fullerenes, 6; and toroidal and Klein-bottle fullerenes, none. Klein-bottle and elliptic fullerenes are the antipodal quotients of centrosymmetric toroidal and spherical fullerenes, respectively. Extensions to infinite systems (plane fullerenes, cylindrical fullerenes, and space fullerenes) are indicated. Eigenvalue spectra of all four classes of finite fullerenes, are reviewed. Leapfrog fullerenes have equal numbers of positive and negative eigenvalues, with 0, 0, 2, or 4 eigenvalues zero for spherical, elliptic, Klein-bottle, and toroidal cases, respectively.
引用
收藏
页码:550 / 558
页数:9
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