Raman spectroscopy study of Ar+ bombardment in highly oriented pyrolytic graphite

被引:30
作者
Jorio, Ado [1 ,2 ]
Lucchese, Marcia M. [2 ]
Stavale, Fernando [2 ]
Achete, Carlos A. [2 ]
机构
[1] Univ Fed Minas Gerais, Dept Fis, BR-30123970 Belo Horizonte, MG, Brazil
[2] Inst Nacl Metrol Normalizacao & Qualidade Ind INM, Div Mat Metrol, BR-25250020 Duque De Caxias, RJ, Brazil
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2009年 / 246卷 / 11-12期
关键词
VACANCY;
D O I
10.1002/pssb.200982314
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In this work, we discuss the effect of low energy Ar+ ion bombardment on highly oriented pyrolytic graphite (HOPG). The evolution of the G and D peak intensities are analyzed as a function of ion dose, as well as the evolution of a broad densityof-states (DOS)-like background. For low ion doses, a small D band is observed. It increases and finally gives place to the broad DOS-like feature. The I-D/I-G, analysis clearly shows three distinct regimes. No frequency shifts are observed, indicating sp(2) bondings are mostly preserved. Comparison between preliminary work on single-layer graphene and HOPG shows the effect observed in HOPG is limited to the top surface. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:2689 / 2692
页数:4
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