Isothermal vapor-liquid equilibria of mixtures of (methanol plus ethanol plus l-propanol or 2-propanol) at 333.15 K

被引：13

作者：

Nagata, I ^{[1
]}

Tamura, K ^{[1
]}

Miyai, K ^{[1
]}

机构：

[1] Kanazawa Univ, Dept Chem & Chem Engn, Div Phys Sci, Kanazawa, Ishikawa 9208667, Japan

来源：

FLUID PHASE EQUILIBRIA | 2000年 / 170卷 / 01期

关键词：

association model; vapor-liquid equilibrium; mixture; pure; alkanol;

D O I：

10.1016/S0378-3812(00)00313-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The UNIQUAC associated-solution theory is extended to reproduce systems containing three alcohols and is applied to binary and ternary mixtures of alcohols. The isothermal vapor-liquid equilibrium data of the liquid mixtures of (methanol + ethanol + 1-propanol) and (methanol + ethanol + 2-propanol) have been measured at 333.15 K using a modified Boublik vapor-recirculating still. The experimental results are analyzed by use of the UNIQUAC associated-solution theory and the UNIQUAC model with binary parameters alone. Both models give comparable results. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：37 / 48

页数：12

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