Remarkably Stable Chalcogen(II) Dications

被引：39

作者：

Martin, Caleb D. ^{[1
]}

Le, Christine M. ^{[1
]}

Ragogna, Paul J. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 42期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

LIGANDS; COMPLEXES; CATALYSTS; CATIONS;

D O I：

10.1021/ja9073968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Air-stable, chalcogen-centered dications have been synthesized and comprehensively characterized. These represent the first diiminopyridine (DIMPY) complexes of the chalcogens as well as the single nonmetallic (sulfur) complex of this ubiquitous ligand. Their stability under ambient conditions is a distinct contrast to other highly charged main-group cations.

引用

页码：15126 / +

页数：4

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