Influences of magnesium particles incorporated on electrophoretically multiwall carbon nanotube film on dye-sensitized solar cell performance

被引:16
作者
Pimanpang, Samuk [1 ]
Maiaugree, Wasan [1 ]
Jarernboon, Wirat [2 ]
Maensiri, Santi [1 ]
Amornkitbamrung, Vittaya [1 ]
机构
[1] Khon Kaen Univ, Fac Sci, Dept Phys, Khon Kaen 40002, Thailand
[2] King Mongkuts Inst Technol Ladkrabang, Fac Sci, Coll Nanotechnol, Bangkok 10520, Thailand
关键词
Dye-sensitized solar cell; Multiwall carbon nanotube; Electrophoretic deposition; FIELD-EMISSION PROPERTIES; NANOCRYSTALLINE TITANIUM-DIOXIDE; COUNTER ELECTRODE; LOW-COST; DEPOSITION; FABRICATION; EFFICIENCY; COMPOSITE;
D O I
10.1016/j.synthmet.2009.07.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Multiwall carbon nanotube (MWCNT) films are prepared on a conductive substrate by electrophoretic deposition. The thickness of MWCNT films is found to increase with the carbon nanotube concentration and the deposition duration. Scanning electron microscopy and energy dispersive X-ray measurements detect magnesium particles incorporated on the MWCNT films. The performance of dye-sensitized solar cell using the electrophoretically MWCNT films as a counter electrode shows a relationship dependent on the film thickness and the amount of magnesium loading. The increase in the magnesium loading on carbon films diminishes the solar cell efficiency. This is because magnesium particles cover the carbon nanotube surface reducing the nanotube catalytic sites and blocking electron transfer to tri-iodide (I(3)(-)) ions. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1996 / 2000
页数:5
相关论文
共 21 条
[1]   The promoting effect of MgO layer in sensitized photodegradation of colorants on TiO2/MgO composite oxide [J].
Bandara, J ;
Kuruppu, SS ;
Pradeep, UW .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 276 (1-3) :197-202
[2]   Preparation of polyaniline/multiwalled carbon nanotube composite by novel electrophoretic route [J].
Dhand, Chetna ;
Arya, Sunil K. ;
Singh, Surinder Pal ;
Singh, Bhanu Pratap ;
Datta, Monika ;
Malhotra, B. D. .
CARBON, 2008, 46 (13) :1727-1735
[3]   Supercapacitors using carbon nanotubes films by electrophoretic deposition [J].
Du, Chunsheng ;
Pan, Ning .
JOURNAL OF POWER SOURCES, 2006, 160 (02) :1487-1494
[4]  
Gao B, 2001, ADV MATER, V13, P1770, DOI 10.1002/1521-4095(200112)13:23<1770::AID-ADMA1770>3.3.CO
[5]  
2-7
[6]   Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :3-14
[7]   Electrophoretic deposition and compression of titania nanoparticle films for dye-sensitized solar cells [J].
Grinis, Larissa ;
Dor, Snir ;
Ofir, Ashi ;
Zaban, Arie .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 198 (01) :52-59
[8]   High-performance carbon counter electrode for dye-sensitized solar cells [J].
Imoto, K ;
Takahashi, K ;
Yamaguchi, T ;
Komura, T ;
Nakamura, J ;
Murata, K .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 79 (04) :459-469
[9]   Optimization of titanium dioxide film prepared by electrophoretic deposition for dye-sensitized solar cell application [J].
Jarernboon, Wirat ;
Pimanpang, Samuk ;
Maensiri, Santi ;
Swatsitang, Ekaphan ;
Amornkitbamrung, Vittaya .
THIN SOLID FILMS, 2009, 517 (16) :4663-4667
[10]   Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder [J].
Kay, A ;
Gratzel, M .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 44 (01) :99-117