Simple synthesis of 1-substituted-4-vinyl-1,2,3-triazoles based on polystyrene-supported sulfonyl chloride

被引：5

作者：

Wang, Zhe ^{[1
,2
]}

Sheng, Shou-Ri ^{[1
,2
]}

Wei, Mei-Hong ^{[1
]}

Liu, Xiao-Ling ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Peoples R China

[2] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2016年 / 46卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Click chemistry; elimination reaction; solid-phase organic synthesis; polystyrene-supported but-3-ynyl sulfonate; 4-vinyl-1,2,3-triazoles; CLICK CHEMISTRY; TERMINAL ALKYNES; MONOMER FAMILY; SOLID-PHASE; CYCLOADDITION; 1,2,3-TRIAZOLES; AZIDES; VINYLTRIAZOLES;

D O I：

10.1080/00397911.2015.1130228

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polystyrene-supported but-3-ynyl sulfonate reagent has been developed and applied to the traceless solid-phase organic synthesis of 1-substituted-4-vinyl-1,2,3-triazoles by CuI-promoted 1,3-dipolar cycloaddition reaction with various organic azides and subsequent cleavage from the polymer support through elimination reaction mediated by 1.8-diazabicyclo[5,4,0]undec-7-ene (DBU). The advantages of this new synthetic method include simple operation and moderate to good yields of the products, as well as good stability of the reagent.

引用

页码：226 / 231

页数：6

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