Numerical method to evaluate the influence of organic solvent absorption on the conductivity of polymeric composites

被引:14
作者
Carrillo, A [1 ]
Martín-Domínguez, IR [1 ]
Rosas, A [1 ]
Márquez, A [1 ]
机构
[1] Inst Mexicano Petr, Mexico City 07730, DF, Mexico
关键词
organic solvent absorption; sensors; liquid leakage;
D O I
10.1016/S0032-3861(02)00558-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A theoretical analysis that describes the change in electric properties of polymeric composites, filled with conductive aggregates, during organic solvent absorption processes is presented in this work. This methodology takes into account the moving boundaries typical of this phenomena; requiring simple numerical procedures to be solved. The results show no numerical instabilities during the calculation process. The obtained results correlate very close to the available experimental data; therefore could be very useful for chemical sensor design. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:6307 / +
页数:8
相关论文
共 20 条
[1]  
BEUGTSSON P, 1993, POLYM ENG SCI, V33, P573
[2]  
BIINGLIN LE, 1992, POLYM ENG SCI, V32, P36
[3]  
BLAZKIEWCZ M, 1993, POLYM ENG SCI, V32, P421
[4]  
Crank J., 1967, MECHANISTIC DIFFUSIO
[5]  
CRRILLO A, 1997, THESIS I TECNOLOGICO
[6]   PERCOLATION PHENOMENA IN POLYMER CARBON COMPOSITES [J].
HSU, WY ;
HOLTJE, WG ;
BARKLEY, JR .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1988, 7 (05) :459-462
[7]   PERCOLATION AND CONDUCTION [J].
KIRKPATRICK, S .
REVIEWS OF MODERN PHYSICS, 1973, 45 (04) :574-588
[8]   COMPUTER-SIMULATION OF THE ELECTRICAL-CONDUCTIVITY OF POLYMER COMPOSITES CONTAINING METALLIC FILLERS [J].
KORTSCHOT, MT ;
WOODHAMS, RT .
POLYMER COMPOSITES, 1988, 9 (01) :60-71
[9]   Array-based vapor sensing using chemically sensitive, carbon black-polymer resistors [J].
Lonergan, MC ;
Severin, EJ ;
Doleman, BJ ;
Beaber, SA ;
Grubb, RH ;
Lewis, NS .
CHEMISTRY OF MATERIALS, 1996, 8 (09) :2298-2312
[10]   PERCOLATION IN ELECTRICAL CONDUCTIVE POLYMER FILLER SYSTEMS .1. DENSITY FILLER CURVES ACCORDING TO A NEW THERMODYNAMIC PERCOLATION MODEL [J].
LUX, F .
POLYMER ENGINEERING AND SCIENCE, 1993, 33 (06) :334-342