Resonances at very low temperature for the reaction D2 + H

被引:2
作者
Simbotin, I. [1 ]
Cote, R. [1 ]
机构
[1] Univ Connecticut, Dept Phys, 2152 Hillside Rd, Storrs, CT 06269 USA
关键词
ultracold chemistry; molecular hydrogen; deuterium; resonances; ULTRACOLD MOLECULES; SCATTERING; COLD; CHEMISTRY; MECHANISM; LI-7(2);
D O I
10.1088/1361-6455/aa6821
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present numerical results for rate coefficients of reaction and vibrational quenching in the collision of H with D-2(v, j) at cold and ultracold temperatures. We explore both ortho-D-2(j = 0) and para-D-2(j = 1) for several initial vibrational states (v <= 5), and find resonant structures in the energy range 0.01-10. K, which are sensitive to the initial rovibrational state (v, j). We compare the reaction rates for D-2 + H with our previously obtained results for the isotopologue reaction H-2 + D, and discuss the implications of our detailed study of this benchmark system for ultracold chemistry.
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页数:10
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  • [1] Perspective: Ultracold molecules and the dawn of cold controlled chemistry
    Balakrishnan, N.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2016, 145 (15)
  • [2] A refined H-3 potential energy surface
    Boothroyd, AI
    Keogh, WJ
    Martin, PG
    Peterson, MR
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (18) : 7139 - 7152
  • [3] Mechanism for the production of vibrationally excited ultracold molecules of Li-7(2)
    Cote, R
    Dalgarno, A
    [J]. CHEMICAL PHYSICS LETTERS, 1997, 279 (1-2) : 50 - 54
  • [4] Mechanism for the production of 6Li2 and 7Li2 ultracold molecules
    Côté, R
    Dalgarno, A
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1999, 195 (02) : 236 - 245
  • [5] Formation of cold Cs2 molecules through photoassociation
    Fioretti, A
    Comparat, D
    Crubellier, A
    Dulieu, O
    Masnou-Seeuws, F
    Pillet, P
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (20) : 4402 - 4405
  • [6] Deuterium chemistry in the primordial gas
    Galli, D
    Palla, F
    [J]. PLANETARY AND SPACE SCIENCE, 2002, 50 (12-13) : 1197 - 1204
  • [7] THE HIGHLY DEUTERATED CHEMISTRY OF THE EARLY UNIVERSE
    Gay, C. D.
    Stancil, P. C.
    Lepp, S.
    Dalgarno, A.
    [J]. ASTROPHYSICAL JOURNAL, 2011, 737 (01)
  • [8] Geometric phase effects in ultracold hydrogen exchange reaction
    Hazra, Jisha
    Kendrick, Brian K.
    Balakrishnan, N.
    [J]. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2016, 49 (19)
  • [9] Observation of Resonances in Penning Ionization Reactions at Sub-Kelvin Temperatures in Merged Beams
    Henson, A. B.
    Gersten, S.
    Shagam, Y.
    Narevicius, J.
    Narevicius, E.
    [J]. SCIENCE, 2012, 338 (6104) : 234 - 238
  • [10] Molecular collisions in ultracold atomic gases
    Hutson, Jeremy M.
    Soldan, Pavel
    [J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2007, 26 (01) : 1 - 28