Iron mediated nitrenoid transfer:: [(η5-C5H5)Fe(CO)2(THF)]+[BF4]- catalyzed aziridination of olefins

被引：42

作者：

Heuss, BD ^{[1
]}

Mayer, MF ^{[1
]}

Dennis, S ^{[1
]}

Hossain, MM ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA

来源：

INORGANICA CHIMICA ACTA | 2003年 / 342卷

关键词：

aziridines; catalysis; iron compounds; nitrenes;

D O I：

10.1016/S0020-1693(02)01145-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron Lewis acid catalyst, [(eta(5)-C5H5)Fe(CO)(2)(THF)](+)[BF4](-), has previously been found to catalyze a growing array of synthetic transformations. Building upon these precedents, the utility of the catalyst has now been extended to catalytic reaction involving olefins and (N-(p -tosyl)imino)phenyliodinane, PhI = NTs, which serves as a nitrenoid precursor, to produce aziridines with yields up to 85%. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：301 / 304

页数：4

共 50 条

[21] Photoinduced configurational instability at iron in the aminocarbene complexes [(η5-C5H5)Fe(CO)(L){=C(NHR2)(CH2R1)}]+BF4-
Davies, SG
Jones, S
Metzler, MR
Yanada, K
Yanada, R
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (05): : 1147 - 1152
[22] Regioselective addition of PRPh2 to the Cα atom of the diphenylallenylidene ligand of [Ru(η5-C5H5) (C=C=CPh2)(CO)(PPri3)]BF4
Esteruelas, MA
Gómez, AV
López, AM
Modrego, J
Oñate, E
ORGANOMETALLICS, 1998, 17 (24) : 5434 - 5436
[23] (η5-C5H5)2TiCl2-catalyzed hydroalumination of α-olefins with Et3Al
Ibragimov, AG
Zagrebel'naya, IV
Satenov, KG
Khalilov, LM
Dzhemilev, UM
RUSSIAN CHEMICAL BULLETIN, 1998, 47 (04) : 691 - 694
[24] CRYSTAL STRUCTURE OF（η5-C5H5）GdCl2（THF）3
Wen Ke Jin Zhong-Sheng Wei Ge-Cheng Chen Wen-QiChangchun Institute of Applied Chemistry
结构化学, 1992, (04) : 244 - 247
[25] Cis-trans isomerization in crystalline [(η5-C5H5)Fe(μ-CO)(CO)]2
Braga, Dario
Chierotti, Michele R.
Garino, Nadia
Gobetto, Roberto
Grepioni, Fabrizia
Polito, Marco
Viale, Alessandra
ORGANOMETALLICS, 2007, 26 (09) : 2266 - 2271
[26] A joint experimental and computational study on the electronic communication in diethynylaryl-bridged (η5-C5H5)Fe(η2-dppe) and (η5-C5H5)Fe(CO)2 units
Medei, Laura
Orian, Laura
Semeikin, Oleg V.
Peterleitner, Mikhail G.
Ustynyuk, Nikolai A.
Santi, Saverio
Durante, Christian
Ricci, Antonella
Lo Sterzo, Claudio
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (13) : 2582 - 2597
[27] Preparation and crystal structures of [μ-SbPh2]2[Mo(CO)2(η5-C5H5)]2•CHCl3, and SbPh[Fe(CO)2(η5-C5H5)]2
Gibbons, MN
Sowerby, DB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) : 289 - 295
[28] Regioselective addition of dienes to the Cβ-Cγ double bond of the allenylidene ligand of [Ru(η5-C5H5)(=C=C=CPh2)(CO)(PiPr3)]BF4
Baya, M
Buil, ML
Esteruelas, MA
López, AM
Oñate, E
Rodríguez, JR
ORGANOMETALLICS, 2002, 21 (09) : 1841 - 1848
[29] CONDENSATION OF PROPIOLIC ESTERS WITH OLEFINS CATALYZED BY THE C5H5FE(CO)2 CATION
ROSENBLUM, M
SCHECK, D
ORGANOMETALLICS, 1982, 1 (02) : 397 - 400
[30] Synthesis and structure of the cubane type [Fe2Sb(CO)5(η5-C5H5)]4 cluster
Konchenko, SN
Virovets, AV
Apenina, SA
Tkachev, SV
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (11) : 555 - 557

← 1 2 3 4 5 →