Photosensitizer-Free, Gold-Catalyzed C-C Cross-Coupling of Boronic Acids and Diazonium Salts Enabled by Visible Light

被引：114

作者：

Witzel, Sina ^{[1
]}

Xie, Jin ^{[1
]}

Rudolph, Matthias ^{[1
]}

Hashmi, A. Stephen K. ^{[1
,2
]}

机构：

[1] Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany

[2] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 09期

关键词：

aryldiazonium salts; boronic acids; C-C coupling; gold catalysis; visible light; PHOTOREDOX CATALYSIS; ORGANOGOLD COMPOUNDS; OXIDATIVE ADDITION; ALKENES; ACTIVATION; REACTIVITY;

D O I：

10.1002/adsc.201700121

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The first photosensitizer-free visible light-driven, gold-catalyzed C-C cross-couplings of arylboronic acids and aryldiazonium salts are reported. The reactions can be conducted under very mild conditions, using a catalytic amount of tris(4-trifluoromethyl)phosphinegold(I) chloride [(4-CF3-C6H4)(3)PAuCl] with methanol as the solvent allowing an alternative access to a variety of substituted biaryls in moderate to excellent yields with broad functional group tolerance.

引用

页码：1522 / 1528

页数：7

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