Photosensitizer-Free, Gold-Catalyzed C-C Cross-Coupling of Boronic Acids and Diazonium Salts Enabled by Visible Light

被引：113
|
作者：
Witzel, Sina [1 ]
Xie, Jin [1 ]
Rudolph, Matthias [1 ]
Hashmi, A. Stephen K. [1 ,2 ]
机构：
[1] Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany
[2] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 09期
关键词：
aryldiazonium salts; boronic acids; C-C coupling; gold catalysis; visible light; PHOTOREDOX CATALYSIS; ORGANOGOLD COMPOUNDS; OXIDATIVE ADDITION; ALKENES; ACTIVATION; REACTIVITY;
D O I：
10.1002/adsc.201700121
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first photosensitizer-free visible light-driven, gold-catalyzed C-C cross-couplings of arylboronic acids and aryldiazonium salts are reported. The reactions can be conducted under very mild conditions, using a catalytic amount of tris(4-trifluoromethyl)phosphinegold(I) chloride [(4-CF3-C6H4)(3)PAuCl] with methanol as the solvent allowing an alternative access to a variety of substituted biaryls in moderate to excellent yields with broad functional group tolerance.
引用
收藏
页码：1522 / 1528
页数：7
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