4-Hydroxymethyl-1-(2,3,4,6-tetra-O-acetyl-ß-D-glucopyranosyl)-1,2,3-triazole

被引：5
作者：
Wilkinson, Brendan L.
Bornaghi, Laurent F.
Houston, Todd A.
Poulsen, Sally-Ann
White, Alan R. [1 ]
机构：
[1] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia
[2] Griffith Univ, Eskitis Inst Cell & Mol Therapies, Brisbane, Qld 4111, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806040864
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, C17H23N3O10, (2), has been determined as part of our investigation into the synthetic utility of the glucosyl triazole unit in carbohydrate chemistry. Compound (2) was synthesized by the 1,3-dipolar cycloaddition reaction of propargyl alcohol with 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl azide under conditions which afforded ( 2) exclusively with complete retention of anomeric stereochemistry. The six-membered carbohydrate ring adopts a chair conformation. The non-H substituents are located in equatorial positions.
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页码：O5065 / O5067
页数：3
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