Sulfated zirconia as a solid acid catalyst for the dehydration of fructose to 5-hydroxymethylfurfural

被引：182

作者：

Qi, Xinhua ^{[1
,2
]}

Watanabe, Masaru ^{[1
]}

Aida, Taku M. ^{[1
]}

Smith, Richard L., Jr. ^{[1
]}

机构：

[1] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] Nankai Univ, Coll Environm Sci & Engn, Minist Educ, Key Lab Pollut Proc & Environm Criteria, Tianjin 300071, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 13期

基金：

中国国家自然科学基金; 日本学术振兴会;

关键词：

Sulfated zirconia; Fructose; 5-Hydroxymethylfurfural; Solid catalyst; ION-EXCHANGE-RESIN; CONVERSION; SO42-/ZRO2; PHOSPHATE; WATER;

D O I：

10.1016/j.catcom.2009.05.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfated zirconia was prepared by impregnation with H2SO4, and was characterized using BET Surface area, XRD, TG-DTA and FNR techniques. The sulfated zirconia was evaluated as a catalyst for the dehydration of fructose to 5-hydroxymethylfurfural (5-HMF) by microwave heating. With sulfated zirconia catalyst, high fructose conversion of 93.6% with 5-HMF yield of 72.8% could be attained at 180 degrees C for 20 min reaction time in acetone-dimethylsulfoxide (DMSO) mixtures. Sulfated zirconia is an effective catalyst for producing 5-HMF from fructose in non-aqueous solvent but shows low catalytic activity in water solvent. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1771 / 1775

页数：5

共 23 条

[1] Kinetics of the decomposition of fructose catalyzed by hydrochloric acid in subcritical water: Formation of 5-hydroxymethylfurfural, levulinic, and formic acids [J].

Asghari, Feridoun Salak ;

Yoshida, Hiroyuki .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (23) :7703-7710

[2] Acid-catalyzed production of 5-hydroxymethyl furfural from D-fructose in subcritical water [J].

Asghari, FS ;

Yoshida, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2163-2173

[3] Preparation of 5-hydroymethylfurfural by dehydration of fructose in the presence of acidic ionic liquid [J].

Bao, Quanxi ;

Qiao, Kun ;

Tomida, Daisuke ;

Yokoyama, Chiaki .

CATALYSIS COMMUNICATIONS, 2008, 9 (06) :1383-1388

[4] Dehydration of D-fructose to hydroxymethylfurfural in sub- and supercritical fluids [J].

Bicker, M ;

Kaiser, D ;

Ott, L ;

Vogel, H .

JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 36 (02) :118-126

[5]

Brei V.V., 2005, THEOR EXP CHEM+, V41, P165

[6] Heterogeneous catalysts based on vanadyl phosphate for fructose dehydration to 5-hydroxymethyl-2-furaldehyde [J].

Carlini, C ;

Patrono, P ;

Galletti, AMR ;

Sbrana, G .

APPLIED CATALYSIS A-GENERAL, 2004, 275 (1-2) :111-118

[7] Selective saccharides dehydration to 5-hydroxymethyl-2-furaldehyde by heterogeneous niobium catalysts [J].

Carlini, C ;

Giuttari, M ;

Galletti, AMR ;

Sbrana, G ;

Armaroli, T ;

Busca, G .

APPLIED CATALYSIS A-GENERAL, 1999, 183 (02) :295-302

[8] Niobic acid and niobium phosphate as highly acidic viable catalysts in aqueous medium: Fructose dehydration reaction [J].

Carniti, Paolo ;

Gervasini, Antonella ;

Biella, Serena ;

Auroux, Aline .

CATALYSIS TODAY, 2006, 118 (3-4) :373-378

[9] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].

Chheda, Juben N. ;

Roman-Leshkov, Yuriy ;

Dumesic, James A. .

GREEN CHEMISTRY, 2007, 9 (04) :342-350

[10] INFLUENCE OF PREPARATION CONDITIONS ON THE STRUCTURE AND CATALYTIC PROPERTIES OF SO42-/ZRO2 SUPERACID CATALYSTS [J].

CORMA, A ;

FORNES, V ;

JUANRAJADELL, MI ;

NIETO, JML .

APPLIED CATALYSIS A-GENERAL, 1994, 116 (1-2) :151-163

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