Tailoring Molecular Self-Assembly of Magnetic Phthalocyanine Molecules on Fe- and Co-Intercalated Graphene

被引：55

作者：

Bazarnik, Maciej ^{[1
]}

Brede, Jens ^{[1
]}

Decker, Regis ^{[1
]}

Wiesendanger, Roland ^{[1
]}

机构：

[1] Univ Hamburg, Inst Appl Phys, D-20355 Hamburg, Germany

来源：

ACS NANO | 2013年 / 7卷 / 12期

关键词：

phthalocyanine; graphene; intercalation; scanning tunneling microscopy; template; surface engineering; SCANNING-TUNNELING-MICROSCOPY; COPPER-PHTHALOCYANINE; METAL PHTHALOCYANINES; INDIVIDUAL MOLECULES; EPITAXIAL GRAPHENE; NANOMESH; SURFACES;

D O I：

10.1021/nn405172q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We investigate molecule molecule, as well as molecule substrate, interactions of phthalocyanine molecules deposited on graphene. In particular, we show how to tune the self-assembly of molecular lattices in two dimensions by intercalation of transition metals between graphene and Ir(111): modifying the surface potential of the graphene layer via intercalation leads to the formation of square, honeycomb, or Kagome lattices. Finally, we demonstrate that such surface induced molecular lattices are stable even at room temperature.

引用

页码：11341 / 11349

页数：9

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