Combustion performance and emissions from torre fi ed and water washed biomass using a kg-scale burner

被引:14
作者
Chen, Chia-Yang [1 ]
Chen, Wei-Hsin [1 ,2 ,3 ]
Hung, Chung-Hsien [4 ,5 ]
机构
[1] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 701, Taiwan
[2] Tunghai Univ, Coll Engn, Dept Chem & Mat Engn, Taichung 407, Taiwan
[3] Natl Chin Yi Univ Technol, Dept Mech Engn, Taichung 411, Taiwan
[4] Cheng Shiu Univ, Ctr Environm Toxin & Emerging Contaminant Res, Kaohsiung 83347, Taiwan
[5] Cheng Shiu Univ, Super Micro Mass Res & Technol Ctr, Kaohsiung 83347, Taiwan
关键词
Torrefaction and combustion; Intermediate waste epoxy resins; Biomass and coal; Persistent organic pollutants (POPs); Water washing; WASTE COOKING OIL; ORGANIC POLLUTANT EMISSIONS; DIBENZO-P-DIOXINS; ENVIRONMENTAL-IMPACT; CHLORINE CONTENT; TORREFACTION; DIESEL; INCINERATION; REDUCTION; SULFUR;
D O I
10.1016/j.jhazmat.2020.123468
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study investigates wastes and biomass as alternative fuels in a kg-scale burner in terms of combustion characteristics and emissions. Water washing, torrefaction, and their combination are used to improve the properties of the wastes and biomass. The air pollutants in the exhaust of the burner are also analyzed. It could be concluded that the reactivity and average heat supply from the pretreatment are improved significantly. The improvement ratio of average heat supply can be up to 103.5 %, stemming from water-soluble ash removal during water washing. Torrefaction can lift the average heat supply due to the increment of fixed carbon content in the fuels, but it reduces the reactivity owing to the decrement of volatile matters. Most of the raw or pre-treated materials can be directly combusted, as a result of lower regulated air pollutants (e.g., NOx, SO2, CO) from them than from coal. Water washing can successfully remove chlorine in the wastes by dissolution since most of the chlorine in the wastes are in salt form. The chlorine reduction significantly reduces the HCl concentration (55-58 % reduction efficiency) and the toxicity concentration of polychlorinated dibenzo-p-dioxins and dibenzofurans (78-84 %), while torrefaction increases the toxicity concentration owing to the de novo synthesis.
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页数:13
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