Ligand-Dependent Ultrasonic-Assistant Self-Assemblies and Photophysical Properties of Lanthanide Nicotinic/Isonicotinic Complexes

被引:76
作者
Chen, Wentong [1 ,2 ]
Fukuzumi, Shunichi [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka, Japan
[2] Jinggangshan Univ, Sch Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China
关键词
CRYSTAL-STRUCTURES; LUMINESCENCE PROPERTIES; COORDINATION POLYMERS; ENERGY-TRANSFER; QUANTUM YIELDS; STATE ENERGIES; TB3+; EUROPIUM; TB(III); PROBE;
D O I
10.1021/ic9000279
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two structural series, including two isomorphous homodinuclear complexes Ln(2)(H2O)(4)(C6NO2H4)(6) (Ln = Tb (1) and Er (2)) and four isostructural one-dimensional (1-D) chain-like assemblies [Ln(H2O)(4)(C6NO2H4)(2)](n)center dot nCl (Ln = Sm (3), Eu (4), Tb (5), and Dy (6)), have been rationally prepared through a facile ultrasonic synthesis and have been characterized by X-ray diffraction and photophysical measurements. Both complexes, 1 and 2, feature a homodinuclear structure, based on two 8-fold coordination lanthanide atoms bridged by four nicotinic acid ligands. Complexes 3-6 are characterized by a 1-D polycationic chain-like structure, containing eight-coordinated lanthanide ions and bridging isonicotinic acid ligands. The 1-D polycationic chains and the isolated chloride anions are interconnected via hydrogen bonds and pi-pi interactions to form a three-dimensional supramolecular network. The effect of nicotinic/isonicotinic acid ligands on the structures and the photoluminescence properties, as well as the relationship between the photoluminescence properties and the structures, was investigated based on IR, UV-vis absorption spectra, low temperature phosphorescent spectra, excitation, and emission spectra. The fluorescence quantum yields of complexes 1 and 2 were determined to be 44% and 21%, respectively.
引用
收藏
页码:3800 / 3807
页数:8
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