Fabrication of copper substrates for surface-enhanced Raman scattering using the microscratching method

被引:10
作者
Zhang, Jingran [1 ,2 ]
Yan, Yongda [1 ,2 ]
Hu, Zhenjiang [2 ]
Zhao, Xuesen [2 ]
机构
[1] Harbin Inst Technol, Inst Robot, State Key Lab Robot & Syst, Harbin 150080, Heilongjiang, Peoples R China
[2] Harbin Inst Technol, Ctr Precis Engn, Harbin, Heilongjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Microscratching; surface-enhanced Raman scattering; micro; nano structures; rhodamine; 6G; NANOPARTICLES;
D O I
10.1177/0954405416666908
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The method of a tip-based microscratching is used to fabricate micro/nano structures on single crystal copper (110) and (111) planes under room temperature. The surface-enhanced Raman scattering enhancement performance of the structured Cu surface has been studied by rhodamine 6G probe molecules. Such micro/nano structures can be machined by varying the scratching parameters such as the feed and the normal load. Experimental results show that the high surface-enhanced Raman scattering enhancement is attributed to the nanostructures formed by pile-ups between adjacent grooves and nanocracks at the bottom of the microsquare. In addition, the Raman intensity of the crystallographic plane (110) is stronger than that of the crystallographic plane (111). This work verifies that the microscratching method is a feasible way to machine active surface-enhanced Raman scattering substrates on Cu surfaces with low cost and high efficiency.
引用
收藏
页码:1310 / 1315
页数:6
相关论文
共 18 条
[1]   Investigation of surface-enhanced Raman scattering from platinum electrodes using a confocal Raman microscope: dependence of surface roughening pretreatment [J].
Cai, WB ;
Ren, B ;
Li, XQ ;
She, CX ;
Liu, FM ;
Cai, XW ;
Tian, ZQ .
SURFACE SCIENCE, 1998, 406 (1-3) :9-22
[2]   Non-labeled virus detection using inverted triangular Au nano-cavities arrayed as SERS-active substrate [J].
Chang, Chia-Wei ;
Liao, Jiunn-Der ;
Shiau, Ai-Li ;
Yao, Chih-Kai .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 156 (01) :471-478
[3]   Nanoporous Copper with Tunable Nanoporosity for SERS Applications [J].
Chen, Lu-Yang ;
Yu, Jin-Shan ;
Fujita, Takeshi ;
Chen, Ming-Wei .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (08) :1221-1226
[4]   An experimental and theoretical investigation into multimode machine tool vibration with surface generation in flycutting [J].
Chen, Wanqun ;
Lu, Lihua ;
Yang, Kai ;
Su, Hao ;
Chen, Guoda .
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART B-JOURNAL OF ENGINEERING MANUFACTURE, 2016, 230 (02) :381-386
[5]   Disordered array of Au covered Silicon nanowires for SERS biosensing combined with electrochemical detection [J].
Convertino, Annalisa ;
Mussi, Valentina ;
Maiolo, Luca .
SCIENTIFIC REPORTS, 2016, 6
[6]   High performance surface-enhanced Raman scattering substrates of Si-based Au film developed by focused ion beam nanofabrication [J].
Gao, Tingting ;
Xu, Zongwei ;
Fang, Fengzhou ;
Gao, Wenlong ;
Zhang, Qing ;
Xu, Xiaoxuan .
NANOSCALE RESEARCH LETTERS, 2012, 7
[7]  
Huo D, 2008, P I MECH ENG B-J ENG, V222, P1, DOI 10.1243/09544054JEM839
[8]   An experimental investigation on micro-milling of polymethyl methacrylate components with nanometric surface roughness [J].
Jiao, Feifei ;
Cheng, Kai .
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART B-JOURNAL OF ENGINEERING MANUFACTURE, 2014, 228 (05) :790-796
[9]   A direct detection of amino acids with surface-enhanced Raman scattering: Cu nanoparticle-coated copper vanadate nanoribbons from mechanochemistry [J].
Lin, Haiyang ;
Shao, Qi ;
Hu, Fei ;
Wang, Hui ;
Shao, Mingwang .
THIN SOLID FILMS, 2014, 558 :385-390
[10]   Probing single molecules and single nanoparticles by surface-enhanced Raman scattering [J].
Nie, SM ;
Emery, SR .
SCIENCE, 1997, 275 (5303) :1102-1106