The thermal and mechanical properties of a polyurethane/multi-walled carbon nanotube composite

被引:317
|
作者
Xiong, Jiawen
Zheng, Zhen
Qin, Xiumin
Li, Ming
Li, Huiqing
Wang, Xinling
机构
[1] Shanghai Jiao Tong Univ, Dept Polymer Sci & Engn, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, Instrumental Anal Ctr, Shanghai 200240, Peoples R China
关键词
carbon nanotubes; chemical treatment; scanning electron microscopy; mechanical properties; microstructure;
D O I
10.1016/j.carbon.2006.04.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A polyurethane/multi-walled carbon nanotube elastomer composite was synthesized. The microstructure of the composite was examined by field-emission scanning electron microscopy and transmission electron microscopy. The thermal and mechanical properties of the composite were characterized by dynamic mechanical thermal analysis, thermogravimetric analysis and tensile testing, The chemical linkage of carbon nanotubes with polyurethane matrix was confirmed by Fourier transform infrared spectra. The study on the structure of the composite showed that carbon nanotubes could be dispersed in the polymer matrix well apart from a few of clusters. The results from thermal analysis indicated that the glass transition temperature of the composite was increased by about 10 degrees C and its thermal stability was obviously improved, in comparison with pure polyurethane. The investigation on the mechanical properties showed that the modulus and tensile strength could be obviously increased by adding 2 wt% (by weight) CNT to the matrix. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2701 / 2707
页数:7
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