Density, Refractive Index, Apparent Specific Volume, and Electrical Conductivity of Aqueous Solutions of Poly(ethylene glycol) 1500 at Different Temperatures

被引:12
作者
Costa, Bernardo de Sa [1 ,2 ]
Garcia-Rojas, Edwin Elard [2 ]
dos Reis Coimbra, Jane Selia [1 ]
Teixeira, Jose Antonio [3 ]
Telis-Romero, Javier [4 ]
机构
[1] Univ Fed Vicosa, Dept Tecnol Alimentos, BR-36570000 Vicosa, MG, Brazil
[2] Univ Fed Fluminense UFF, Dept Engn Agronegocios, BR-27225250 Volta Redonda, RJ, Brazil
[3] Univ Minho UMinho, Ctr Engn Biol, P-47710057 Braga, Portugal
[4] Univ Estadual Paulista, Inst Biociencias Letras & Ciencias Exatas, Dept Tecnol & Engn Alimentos, BR-15054000 Sao Jose Do Rio Preto, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
BOVINE SERUM-ALBUMIN; CITRATE PLUS WATER; BINARY-MIXTURES; PARTIAL-PURIFICATION; KINEMATIC VISCOSITY; TERNARY MIXTURES; 2-PHASE SYSTEMS; PEG; BEHAVIOR; PHOSPHATE;
D O I
10.1021/je400802t
中图分类号
O414.1 [热力学];
学科分类号
摘要
Thermophysical properties of aqueous solutions of poly(ethylene glycol) 1500 g.mol(-1) were measured as a function of polymer concentration w = (0.05, 0.10, 0.15, 0.20 and 0.25) and temperature T/K = (288, 293, 298, 303 and 308). Aqueous systems composed of poly(ethylene glycol) are frequently used in processes involving the separation of biological compounds. The density of the solutions varied from (1001.68 to 1042.65) kg.m(-3), the refractive index ranged from (1.3377 to 1.3681), the apparent specific volume was between (0.8336 and 0.8528) g.cm(-3), and the electrical conductivity varied between (66.22 and 170.29) 10(-3) mS.cm(-1). Polynomial models for the properties as a function of temperature and poly(ethylene glycol) 1500 g.mol(-1) concentration were fitted to the experimental data. Models accounting for combined effects between variables are particularly useful in industrial applications in which physical parameters must be promptly and accurately calculated.
引用
收藏
页码:339 / 345
页数:7
相关论文
共 31 条
[1]   Multiple administration of PEG-coated liposomal oxaliplatin enhances its therapeutic efficacy: A possible mechanism and the potential for clinical application [J].
Abu Lila, Amr S. ;
Eldin, Noha Essam ;
Ichihara, Masako ;
Ishida, Tatsuhiro ;
Kiwada, Hiroshi .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2012, 438 (1-2) :176-183
[2]   Partitioning of whey proteins, bovine serum albumin and porcine insulin in aqueous two-phase systems [J].
Alves, JGLF ;
Chumpitaz, LDA ;
da Silva, LHM ;
Franco, TT ;
Meirelles, AJA .
JOURNAL OF CHROMATOGRAPHY B, 2000, 743 (1-2) :235-239
[3]   Rotavirus-like particles primary recovery from insect cells in aqueous two-phase systems [J].
Benavides, Jorge ;
Mena, Jimmy A. ;
Cisneros-Ruiz, Mayra ;
Ramirez, Octavio T. ;
Palomares, Laura A. ;
Rito-Palomares, Marco .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2006, 842 (01) :48-57
[4]   Rheological Behavior of Binary Aqueous Solutions of Poly(ethylene glycol) of 1500 g.mol-1 as Affected by Temperature and Polymer Concentration [J].
Costa, Bernardo de Sa ;
dos Reis Coimbra, Jane Selia ;
Martins, Marcio Aredes ;
Garcia-Rojas, Edwin Elard ;
Telis-Romero, Javier ;
De Oliveira, Eduardo Basilio .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (04) :838-844
[5]   Kinematic viscosities of poly(ethylene glycols) [J].
Cruz, MS ;
Chumpitaz, LDA ;
Alves, JGLF ;
Meirelles, AJA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (01) :61-63
[6]   Volumetric Study of Aqueous Solutions of Polyethylene Glycol as a Function of the Polymer Molar Mass in the Temperature Range 283.15 to 313.15 K and 0.1 MPa [J].
Cruz, Raphael da C. ;
Martins, Rosana J. ;
Cardoso, Marcio J. E. de M. ;
Barcia, Oswaldo E. .
JOURNAL OF SOLUTION CHEMISTRY, 2009, 38 (08) :957-981
[7]   Partitioning of glycomacropeptide in aqueous two-phase systems [J].
da Silva, C. A. S. ;
Coimbra, J. S. R. ;
Rojas, E. E. G. ;
Teixeira, J. A. C. .
PROCESS BIOCHEMISTRY, 2009, 44 (11) :1213-1216
[8]  
Durchschlag H., 1986, SPECIFIC VOLUMES BIO, P45
[9]   Densities of poly(ethylene glycol) plus water mixtures in the 298.15-328.15 K temperature range [J].
Eliassi, A ;
Modarress, H .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (05) :719-721
[10]   DENSITY AND VISCOSITY OF CONCENTRATED AQUEOUS-SOLUTIONS OF POLYETHYLENE-GLYCOL [J].
GONZALEZTELLO, P ;
CAMACHO, F ;
BLAZQUEZ, G .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (03) :611-614