5,5′-Bis-(trinitromethyl)-3,3′-bi-(1,2,4-oxadiazole): a stable ternary CNO-compound with high density

被引：81

作者：

Kettner, M. A. ^{[1
]}

Klapoetke, T. M. ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 18期

关键词：

ENERGETIC MATERIALS; NITRATION; CRYSTALS;

D O I：

10.1039/c3cc49879d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5,5'-Bis-(trinitromethyl)-3,3'-bi-(1,2,4-oxadiazole) is a new ternary CNO-compound. It has been synthesized by nitration of diammonium 5,5'-bis-(dinitromethanide)-3,3'-bi-(1,2,4-oxadiazole) with nitronium tetrafluoroborate. Single crystal X-ray diffraction studies show a remarkable high density. Thermal stability and sensitivities of the new compound were determined by differential scanning calorimetry (DSC) and standardized drop hammer and friction tests.

引用

页码：2268 / 2270

页数：3

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