Formation and corrosion behavior of Fe-based amorphous metallic coatings by HVOF thermal spraying

被引:228
作者
Zhou, Z. [1 ,2 ]
Wang, L. [2 ]
Wang, F. C. [2 ]
Zhang, H. F. [3 ]
Liu, Y. B. [2 ]
Xu, S. H. [2 ]
机构
[1] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
[2] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[3] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
关键词
Fe-based amorphous coating; HVOF; Microstructure; Corrosion resistance; SUPERCOOLED LIQUID; GLASSY ALLOYS; BULK; STRENGTH; RESISTANCE; MECHANISMS; DIFFERENCE; NI;
D O I
10.1016/j.surfcoat.2009.08.025
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
coatings with a composition of Fe48Cr15Mo14C15B6Y2 were prepared by means of high velocity oxygen fuel (HVOF) thermal spraying under different conditions. Microstructural studies show that the coatings present dense layered structure and low porosity with a fraction of nanocrystals precipitated. The porosity and fraction of the coatings decrease as the kerosene and oxygen flow increase within the parameter range examined. Corrosion behavior of the amorphous coatings was investigated by electrochemical measurement. The results show that the coatings are spontaneously passivated with wide passive region and low passive current density in 3.5% NaCl. 1 N HCl and 1 N H2SO4 solutions. and exhibit an excellent ability to resist localized corrosion. However, the corrosion resistance of the coatings decreases in 1 N NaOH solution with lower transpassive potential and passive region. In addition, the optimal spraying parameter improves the corrosion resistance of the amorphous coatings obviously due to the proper proportion of porosity and amorphous fraction. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:563 / 570
页数:8
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