Novel amido-bridged dinuclear iridium(III) and iridium(II) complexes. Synthesis and characterization of [CpIr(mu(2)-NHC6H4R-p)(3)IrCp]Cl (Cp* = eta(5)-C5Me5; R = Me, H, Cl, CF3), [CpIr{(mu(2)-NH)(2)C10H6-1,8}(mu(2)-X)IrCp]X (X = Cl, Br), CpIr{(mu(2)-NH)(2)C10H6-1,8}IrCp, and [CpIr{(mu(2)-NH)(2)C10H6-1,8}(mu(2)-H)IrCp]O2CCF3

被引：16

作者：

Matsuzaka, H ^{[1
]}

Ariga, K ^{[1
]}

Kase, H ^{[1
]}

Kamura, T ^{[1
]}

Kondo, M ^{[1
]}

Kitagawa, S ^{[1
]}

Yamasaki, M ^{[1
]}

机构：

[1] RIGAKU CORP,XRAY RES LAB,AKISHIMA,TOKYO 196,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 21期

关键词：

D O I：

10.1021/om970499e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel amido-bridged dinuclear Ir(III) and Ir(ll) complexes of the forms [Cp*Ir(mu(2)-NHC6H4R-p)(3)IrCp*]Cl (2.Cl: 2a, R = Me; 2b, R = H; 2c, R = CI; 2d, R = CF3), [Cp*Ir{(mu(2)-NH)(2)C10H6-1,8}-(mu(2)-X)IrCp*]X (4a, X = CI; 4b, X = Br), Cp*Ir{(mu(2)-NH)(2)C10H6-1,8}IrCp* (5), and [Cp*Ir{(mu 2-NH)(2)C10H6-1,8}(mu(2)-H)IrCp*]O2CCF3 (6) were prepared from [Cp*IrX(mu(2)-X)](2) (la, X = CI; Ib, X = Br) and the corresponding LiNHR species. The molecular structures of 2a.ClO4 and 5 have been determined by X-ray crystallography.

引用

页码：4514 / 4516

页数：3

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