Preparation and lithium insertion behaviour of LiyNa1.2-yV3O8

被引：24

作者：

Kawakita, J

Makino, K

Katayama, Y

Miura, T

Kishi, T

机构：

来源：

SOLID STATE IONICS | 1997年 / 99卷 / 3-4期

关键词：

lithium; sodium; vanadate; ion exchange; molten salt;

D O I：

10.1016/S0167-2738(97)00255-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The layered compounds, LiyNa1.2-yV3O8, have been obtained by the ion exchange reaction of Na1.2V3O8 in the molten nitrates containing Li+ and Na+ ions with various ratios. Electrochemical measurements showed only two steps of the lithium insertion process of these vanadates and increase in the discharge capacity for y = 0.21. The third step, with the phase transition, has been found to be a characteristic of Li1.2V3O8.

引用

收藏

页码：165 / 171

页数：7

相关论文

共 14 条

[1] STRUCTURAL CHARACTERIZATION OF LI1+XV3O8 INSERTION ELECTRODES BY SINGLE-CRYSTAL X-RAY-DIFFRACTION [J].

DEPICCIOTTO, LA ;

ADENDORFF, KT ;

LILES, DC ;

THACKERAY, MM .

SOLID STATE IONICS, 1993, 62 (3-4) :297-307

[2] RECHARGEABLE LI/LI1+XV3O8 CELLS [J].

PANERO, S ;

PASQUALI, M ;

PISTOIA, G .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (05) :1225-1227

[3] LI/LI1+XV3O8 BATTERIES .5. COMPARISON WITH OTHER SECONDARY CELLS AND INFLUENCE OF MICRO-STRUCTURAL AND MACRO-STRUCTURAL ALTERATIONS ON THE CATHODE PERFORMANCE [J].

PASQUALI, M ;

PISTOIA, G ;

MANEV, V ;

MOSHTEV, RV .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (12) :2454-2458

[4] LITHIUM INTERCALATION IN NA1+XV3O8 SYNTHESIZED BY A SOLUTION TECHNIQUE [J].

PASQUALI, M ;

PISTOIA, G .

ELECTROCHIMICA ACTA, 1991, 36 (10) :1549-1553

[5] LI/LI1+X V3O8 SECONDARY BATTERIES .3. FURTHER CHARACTERIZATION OF THE MECHANISM OF LI+ INSERTION AND OF THE CYCLING BEHAVIOR [J].

PISTOIA, G ;

PASQUALI, M ;

TOCCI, M ;

MOSHTEV, RV ;

MANER, V .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (02) :281-284

[6] MIXED NA/K VANADATES FOR RECHARGEABLE LI BATTERIES [J].

PISTOIA, G ;

WANG, G ;

ZANE, D .

SOLID STATE IONICS, 1995, 76 (3-4) :285-290

[7] LI/LI1+XV3O8 SECONDARY BATTERIES - SYNTHESIS AND CHARACTERIZATION OF AN AMORPHOUS FORM OF THE CATHODE [J].

PISTOIA, G ;

PASQUALI, M ;

WANG, G ;

LI, L .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (08) :2365-2370

[8] SOLID-SOLUTIONS LI1+XV3O8 AS CATHODES FOR HIGH-RATE SECONDARY LI BATTERIES [J].

PISTOIA, G ;

PANERO, S ;

TOCCI, M ;

MOSHTEV, RV ;

MANEV, V .

SOLID STATE IONICS, 1984, 13 (04) :311-318

[9] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767

[10] ELECTROCHEMICAL, XAS AND FTIR STUDY OF LITHIUM INTERCALATION IN NA1+XV3O8 [J].

TOSSICI, R ;

MARASSI, R ;

BERRETTONI, M ;

STIZZA, S ;

PISTOIA, G .

SOLID STATE IONICS, 1993, 67 (1-2) :77-83