Sustainable green solvents for microextraction techniques: Recent developments and applications

被引:71
作者
Carasek, Eduardo [1 ]
Bernardi, Gabrieli [1 ]
Morelli, Diogo [1 ]
Merib, Josias [2 ]
机构
[1] Univ Fed Santa Catarina, Dept Quim, BR-88040900 Florianopolis, SC, Brazil
[2] Univ Fed Ciencias Saude Porto Alegre, Dept Farmacociencias, BR-90050170 Porto Alegre, RS, Brazil
关键词
Deep eutectic solvents; Switchable hydrophilicity solvents; Supramolecular solvents; Sample preparation; High-throughput; DEEP EUTECTIC SOLVENTS; LIQUID-LIQUID MICROEXTRACTION; CHROMATOGRAPHY-MASS-SPECTROMETRY; PHASE MICROEXTRACTION; CHOLINE CHLORIDE; WATER SAMPLES; SUPRAMOLECULAR SOLVENTS; EXTRACTION-SOLVENT; CARBOXYLIC-ACIDS; AQUEOUS SAMPLES;
D O I
10.1016/j.chroma.2021.461944
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The development and application of alternative green solvents in analytical techniques consist of trends in sample preparation, since this subject represents an important step toward sustainability in experimental procedures. This review is focused on the main theoretical aspects related to deep eutectic solvents (DES), switchable hydrophilicity solvents (SHS) and supramolecular solvents (SUPRAS). Recent applications are highlighted, particularly for the extraction of different analytes from environmental, biological and food matrices. Moreover, novel configurations are emphasized, aiming for efficient, automated and high-throughput procedures. This review also provides some critical points regarding the use of these solvents and their green aspects. (c) 2021 Elsevier B.V. All rights reserved.
引用
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页数:10
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