Sustainable green solvents for microextraction techniques: Recent developments and applications

被引:71
作者
Carasek, Eduardo [1 ]
Bernardi, Gabrieli [1 ]
Morelli, Diogo [1 ]
Merib, Josias [2 ]
机构
[1] Univ Fed Santa Catarina, Dept Quim, BR-88040900 Florianopolis, SC, Brazil
[2] Univ Fed Ciencias Saude Porto Alegre, Dept Farmacociencias, BR-90050170 Porto Alegre, RS, Brazil
关键词
Deep eutectic solvents; Switchable hydrophilicity solvents; Supramolecular solvents; Sample preparation; High-throughput; DEEP EUTECTIC SOLVENTS; LIQUID-LIQUID MICROEXTRACTION; CHROMATOGRAPHY-MASS-SPECTROMETRY; PHASE MICROEXTRACTION; CHOLINE CHLORIDE; WATER SAMPLES; SUPRAMOLECULAR SOLVENTS; EXTRACTION-SOLVENT; CARBOXYLIC-ACIDS; AQUEOUS SAMPLES;
D O I
10.1016/j.chroma.2021.461944
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The development and application of alternative green solvents in analytical techniques consist of trends in sample preparation, since this subject represents an important step toward sustainability in experimental procedures. This review is focused on the main theoretical aspects related to deep eutectic solvents (DES), switchable hydrophilicity solvents (SHS) and supramolecular solvents (SUPRAS). Recent applications are highlighted, particularly for the extraction of different analytes from environmental, biological and food matrices. Moreover, novel configurations are emphasized, aiming for efficient, automated and high-throughput procedures. This review also provides some critical points regarding the use of these solvents and their green aspects. (c) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数:10
相关论文
共 112 条
[1]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[2]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[3]   Switchable-hydrophilicity solvent liquid-liquid microextraction versus dispersive liquid-liquid microextraction prior to HPLC-UV for the determination and isolation of piperine from Piper nigrum L [J].
Al-Nidawi, Mais ;
Alshana, Usama ;
Caleb, Jude ;
Hassan, Malek ;
Rahman, Zia Ur ;
Hanoglu, Duygu Yigit ;
Calis, Ihsan .
JOURNAL OF SEPARATION SCIENCE, 2020, 43 (15) :3053-3060
[4]   Development of combined-supramolecular microextraction with ultra-performance liquid chromatography-tandem mass spectrometry procedures for ultra-trace analysis of carbaryl in water, fruits and vegetables [J].
ALOthman, Zeid A. ;
Yilmaz, Erkan ;
Habila, Mohamed A. ;
Alhenaki, Bushra ;
Soylak, Mustafa ;
Ahmed, A. Y. Badjah Hadj ;
Alabdullkarem, Eman A. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2022, 102 (07) :1491-1501
[5]   Supramolecular solvent microextraction and ultra-performance liquid chromatography-tandem mass spectrometry combination for the preconcentration and determination of malathion in environmental samples [J].
ALOthman, Zeid A. ;
Yilmaz, Erkan ;
Habila, Mohamed A. ;
Ghfar, Ayman A. ;
Alhenaki, Bushra ;
Soylak, Mustafa ;
Ahmed, A. Y. Badjah Hadj .
DESALINATION AND WATER TREATMENT, 2019, 144 :166-171
[6]   Switchable-hydrophilicity solvent liquid-liquid microextraction [J].
Alshana, Usama ;
Hassan, Malek ;
Al-Nidawi, Mais ;
Yilmaz, Erkan ;
Soylak, Mustafa .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2020, 131
[7]   Simple and Green Heat-Induced Deep Eutectic Solvent Microextraction for Determination of Lead and Cadmium in Vegetable Samples by Flame Atomic Absorption Spectrometry: a Multivariate Study [J].
Altunay, Nail ;
Elik, Adil ;
Bingol, Deniz .
BIOLOGICAL TRACE ELEMENT RESEARCH, 2020, 198 (01) :324-331
[8]   Preparation and application of alcohol based deep eutectic solvents for extraction of curcumin in food samples prior to its spectrophotometric determination [J].
Altunay, Nail ;
Elik, Adil ;
Gurkan, Ramazan .
FOOD CHEMISTRY, 2020, 310
[9]   Efficient environment friendly method for microextraction of dinitroaniline herbicides using supramolecular solvent [J].
Amir, Salma ;
Jan, Muhammad Rasul ;
Shah, Jasmin .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2021, 101 (10) :1393-1407
[10]   The role of green extraction techniques in Green Analytical Chemistry [J].
Armenta, Sergio ;
Garrigues, Salvador ;
de la Guardia, Miguel .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2015, 71 :2-8