An iron (II) complex containing well-resolved 1D water chain and 1D chain of copper (II) complex with bis(tetrazoly)amine: Syntheses, crystal structures and properties

被引：9

作者：

Guan, Yang-Fan ^{[1
]}

Zhou, Ai-Ju ^{[1
]}

Wang, Dong-Yao ^{[1
]}

Wang, Jing ^{[1
]}

Dong, Wen ^{[1
]}

机构：

[1] Guangzhou Univ, Dept Chem, Guangzhou 510006, Guangdong, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 938卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

H(2)bta; Water cluster; 1D chain; Crystal structure; SUPRAMOLECULAR COMPLEX; CLUSTER; MOLECULES; H(2)BTA; LIGANDS; MOTIFS; LAYERS;

D O I：

10.1016/j.molstruc.2009.09.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two H(2)bta supramolecular complexes. [Fe(bpy)(2)(bta)] 6H(2)O (1) and [Cu(Hbta)(2)] 4H(2)O (2) (bpy = 2,2'-bipyridine, H(2)bta = bis(tetrazoly)amine). have been synthesized and characterized by single crystal X-ray diffraction analysis In mononuclear complex 1 a well-resolved water chain formed by hydrogen-bonding interactions has been observed, while 2 possesses a 1D spiral chain structure. The cyclic voltammogram (CV) of H(2)bta ligand and 1 have been investigated and the E-p = -0.308 V for H(2)bta ligand and E-p = -0.365 V for 1 may be attributed to the oxidation process of bta(-) - e -> bta and the negative value of E-p show the H(2)bta can act as a good reducing ligand. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.

引用

页码：150 / 155

页数：6

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