On-Board Hydrogen Production Through Catalytic Exhaust-Gas Reforming of Isooctane: Efficiency of Mixed Oxide Catalysts Ce2Zr1.5Me0.5O8 (Me = Co, Rh, or Co-Noble Metal) On-Board H2 from Fuel Reforming on Doped Mixed Oxides in EGR

被引:13
作者
Ambroise, Emmanuelle [1 ]
Courson, Claire [1 ]
Kiennemann, Alain [1 ]
Roger, Anne-Cecile [1 ]
Pajot, Olivier [2 ]
Samson, Erwann [2 ]
Blanchard, Gilbert [2 ]
机构
[1] Lab Mat Surfaces & Procedes Catalyse, F-67087 Strasbourg, France
[2] Ctr Tech VELIZY Sci Automobile & Rech Avancee, Sci & Technol Emergentes Post Traitement PSA, F-78943 Velizy Villacoublay, France
关键词
Hydrogen; EGR; Reforming; Cobalt-Noble Metal-Ceria-Zirconia; COBALT CATALYSTS; 3-WAY CATALYSIS; DIESEL-ENGINE; STEAM; RECIRCULATION; GASOLINE; GENERATION; SUPPORT;
D O I
10.1007/s11244-009-9386-y
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Isooctane reforming under conditions which are set by exhaust gas can be built on to generate hydrogen on-board. Isooctane reforming reactivity tests have been performed with bimetallic catalysts Co-Noble Metal/ceriazirconia. Variable activity of noble metals doped catalysts, depending on the nature of the noble metal, its loading, and affected by the activation process, is discussed.
引用
收藏
页码:2101 / 2107
页数:7
相关论文
共 31 条
[1]   Catalytic autothermal reforming of methane and propane over supported metal catalysts [J].
Ayabe, S ;
Omoto, H ;
Utaka, T ;
Kikuchi, R ;
Sasaki, K ;
Teraoka, Y ;
Eguchi, K .
APPLIED CATALYSIS A-GENERAL, 2003, 241 (1-2) :261-269
[2]   STEAM EFFECTS IN 3-WAY CATALYSIS [J].
BARBIER-JR, J ;
DUPREZ, D .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1994, 4 (2-3) :105-140
[3]   REVERSIBILITY OF HYDROGEN CHEMISORPTION ON A CERIA-SUPPORTED RHODIUM CATALYST [J].
BERNAL, S ;
CALVINO, JJ ;
CIFREDO, GA ;
RODRIGUEZIZQUIERDO, JM ;
PERRICHON, V ;
LAACHIR, A .
JOURNAL OF CATALYSIS, 1992, 137 (01) :1-11
[4]   Efficient bimetallic catalysts for hydrogen generation from diesel fuel [J].
Cheekatamarla, PK ;
Lane, AM .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2005, 30 (11) :1277-1285
[5]   Hydrogen production by ethanol reforming over Rh/CeO2-ZrO2 catalysts [J].
Diagne, C ;
Idriss, H ;
Kiennemann, A .
CATALYSIS COMMUNICATIONS, 2002, 3 (12) :565-571
[6]   Role of the oxide support on the performance of Rh catalysts for the autothermal reforming of gasoline and gasoline surrogates to hydrogen [J].
Ferrandon, Magali ;
Krause, Theodore .
APPLIED CATALYSIS A-GENERAL, 2006, 311 (135-145) :135-145
[7]   Development of cobalt catalysts for the steam reforming of naphthalene as a model compound of tar derived from biomass gasification [J].
Furusawa, T ;
Tsutsumi, A .
APPLIED CATALYSIS A-GENERAL, 2005, 278 (02) :195-205
[8]   Reforming of isooctane over Ni-Al2O3 catalysts for hydrogen production:: Effects of catalyst preparation method and nickel loading [J].
Ibrahim, Hussam H. ;
Kumar, Prashant ;
Idem, Raphael O. .
ENERGY & FUELS, 2007, 21 (02) :570-580
[9]   Fischer-Tropsch synthesis: support, loading, and promoter effects on the reducibility of cobalt catalysts [J].
Jacobs, G ;
Das, TK ;
Zhang, YQ ;
Li, JL ;
Racoillet, G ;
Davis, BH .
APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) :263-281
[10]   ON-BOARD GENERATION OF HYDROGEN-RICH GASEOUS FUELS - A REVIEW [J].
JAMAL, Y ;
WYSZYNSKI, ML .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1994, 19 (07) :557-572