Titanocene dichloride-Lewis base: An efficient catalytic system for coupling of epoxides and carbon dioxide

被引：37

作者：

Bai, Dongsheng ^{[1
]}

Jing, Huanwang ^{[1
]}

Liu, Qiang ^{[1
]}

Zhu, Qianqian ^{[1
]}

Zhao, Xiaofang ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 11卷 / 03期

关键词：

Epoxides; Carbon dioxide; Titanocene dichloride; Coupling reaction; Cyclic carbonate; CYCLIC CARBONATES; ALUMINUM PORPHYRIN; PROPYLENE-OXIDE; CHROMIUM PORPHYRIN; CYCLOHEXENE OXIDE; SALEN COMPLEXES; IONIC LIQUIDS; CO2; COPOLYMERIZATION; POLYCARBONATE;

D O I：

10.1016/j.catcom.2009.09.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalysts composed of titanocene dichloride (Cp2TiCl2) and Lewis base were developed to catalyze the coupling reaction of epoxides and CO2 under mild conditions to generate the relevant cyclic carbonates. The effects of reaction variables on the catalytic performance were studied in detail and indicated an optimized reaction temperature of 150 degrees C, solvent tetrahydrofuran (THF) and tetrabutylammonium bromide (TBAB) as Lewis base. Under the optimized reaction condition, styrene carbonate was obtained in 98.5% yield within 45 min. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：155 / 157

页数：3

共 38 条

[1] ALTERNATING COPOLYMERIZATION OF CARBON-DIOXIDE AND EPOXIDE CATALYZED BY THE ALUMINUM PORPHYRIN-QUATERNARY ORGANIC SALT OR TRIPHENYLPHOSPHINE SYSTEM - SYNTHESIS OF POLYCARBONATE WITH WELL-CONTROLLED MOLECULAR-WEIGHT [J].

AIDA, T ;

ISHIKAWA, M ;

INOUE, S .

MACROMOLECULES, 1986, 19 (01) :8-13

[2] SYNTHESIS OF POLYETHER POLYCARBONATE BLOCK CO-POLYMER FROM CARBON-DIOXIDE AND EPOXIDE USING A METALLOPORPHYRIN CATALYST SYSTEM [J].

AIDA, T ;

INOUE, S .

MACROMOLECULES, 1982, 15 (02) :682-684

[3] ACTIVATION OF CARBON-DIOXIDE WITH ALUMINUM PORPHYRIN AND REACTION WITH EPOXIDE - STUDIES ON (TETRAPHENYLPORPHINATO)ALUMINUM ALKOXIDE HAVING A LONG OXYALKYLENE CHAIN AS THE ALKOXIDE GROUP [J].

AIDA, T ;

INOUE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (05) :1304-1309

[4] CARBONATE FORMATION FROM OXIRANES AND CARBON-DIOXIDE CATALYZED BY ORGANOTIN HALIDE-TETRAALKYLPHOSPHONIUM HALIDE-COMPLEXES [J].

BABA, A ;

NOZAKI, T ;

MATSUDA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (04) :1552-1554

[5] REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES [J].

BRAUNSTEIN, P ;

MATT, D ;

NOBEL, D .

CHEMICAL REVIEWS, 1988, 88 (05) :747-764

[6] Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts [J].

Caló, V ;

Nacci, A ;

Monopoli, A ;

Fanizzi, A .

ORGANIC LETTERS, 2002, 4 (15) :2561-2563

[7] A practical route to enantiopure 1,2-aminoalcohols [J].

Chang, HT ;

Sharpless, KB .

TETRAHEDRON LETTERS, 1996, 37 (19) :3219-3222

[8] Quaternary onium tribromide catalyzed cyclic carbonate synthesis from carbon dioxide and epoxides [J].

Chang, Tao ;

Jing, Huanwang ;

Jin, Lili ;

Qiu, Wenyuan .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 264 (1-2) :241-247

[9] Copolymerization of CO2 and epoxides catalyzed by metal salen complexes [J].

Darensbourg, DJ ;

Mackiewicz, RM ;

Phelps, AL ;

Billodeaux, DR .

ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (11) :836-844

[10] Catalysts for the reactions of epoxides and carbon dioxide [J].

Darensbourg, DJ ;

Holtcamp, MW .

COORDINATION CHEMISTRY REVIEWS, 1996, 153 :155-174

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