A luminescent silver(I) carbene stair polymer

被引：103
作者：
Liu, QX [1 ]
Xu, FB [1 ]
Li, QS [1 ]
Zeng, XS [1 ]
Leng, XB [1 ]
Chou, YL [1 ]
Zhang, ZZ [1 ]
机构：
[1] Nankai Univ, State Key Lab Element Organ Chem, Tianjin 300071, Peoples R China
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 02期
关键词：
D O I：
10.1021/om020572n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1-(9-Anthracenylmethyl)-3-ethylimidazolium iodide was heated in CH2Cl2 solution with silver oxide to afford a stair polymer of N-heterocyclic carbene silver(I), which gave strong anthracene-type fluorescence. The carbene moiety could be displaced from this polymer by pyridine to afford a known polymer with a similar shape but a tighter framework; this polymer showed an emission band at 579 nm arising from a Ag-Ag interaction.
引用
收藏
页码：309 / 314
页数：6
相关论文
共 32 条
  • [1] ELECTRON-DISTRIBUTION IN A STABLE CARBENE
    ARDUENGO, AJ
    DIAS, HVR
    DIXON, DA
    HARLOW, RL
    KLOOSTER, WT
    KOETZLE, TF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) : 6812 - 6822
  • [2] A STABLE CRYSTALLINE CARBENE
    ARDUENGO, AJ
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
  • [3] A STABLE DIAMINOCARBENE
    ARDUENGO, AJ
    GOERLICH, JR
    MARSHALL, WJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (44) : 11027 - 11028
  • [4] HOMOLEPTIC CARBENE SILVER(I) AND CARBENE COPPER(I) COMPLEXES
    ARDUENGO, AJ
    DIAS, HVR
    CALABRESE, JC
    DAVIDSON, F
    [J]. ORGANOMETALLICS, 1993, 12 (09) : 3405 - 3409
  • [5] ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES
    ARDUENGO, AJ
    DIAS, HVR
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5530 - 5534
  • [6] SYNTHESIS OF NEW IMIDAZOLE DERIVATIVES AS POTENTIAL INHIBITORS OF THROMBOXANE SYNTHETASE .2.
    BANFI, A
    BENEDINI, F
    SALA, A
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1991, 28 (02) : 401 - 404
  • [7] Electronic structure of stable carbenes, silylenes, and germylenes
    Boehme, C
    Frenking, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (08) : 2039 - 2046
  • [8] Stable carbenes
    Bourissou, D
    Guerret, O
    Gabbaï, FP
    Bertrand, G
    [J]. CHEMICAL REVIEWS, 2000, 100 (01) : 39 - 91
  • [9] *BRUK AN XRAY SYST, 1998, SMART 5 0 SAINT 4 0
  • [10] 1,1′-(pyridine-2,6-diyl)bis(3-benzyl-2,3-dihydro-1H-immidazol-2-ylidene), a new multidentate N-heterocyclic biscarbene and its silver(I) complex derivative
    Caballero, A
    Díez-Barra, E
    Jalón, FA
    Merino, S
    Tejeda, J
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 395 - 398
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