A luminescent silver(I) carbene stair polymer

被引:103
|
作者
Liu, QX [1 ]
Xu, FB [1 ]
Li, QS [1 ]
Zeng, XS [1 ]
Leng, XB [1 ]
Chou, YL [1 ]
Zhang, ZZ [1 ]
机构
[1] Nankai Univ, State Key Lab Element Organ Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1021/om020572n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
1-(9-Anthracenylmethyl)-3-ethylimidazolium iodide was heated in CH2Cl2 solution with silver oxide to afford a stair polymer of N-heterocyclic carbene silver(I), which gave strong anthracene-type fluorescence. The carbene moiety could be displaced from this polymer by pyridine to afford a known polymer with a similar shape but a tighter framework; this polymer showed an emission band at 579 nm arising from a Ag-Ag interaction.
引用
收藏
页码:309 / 314
页数:6
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