Investigation and prediction of the salting-out effect of methane in various aqueous electrolyte solutions

被引：15

作者：

Kim, Kwangmin ^{[1
]}

Seo, Kyeongjun ^{[1
]}

Lee, Jaewon ^{[1
]}

Kim, Myung-Gil ^{[2
]}

Ha, Kyoung-Su ^{[1
]}

Kim, Choongik ^{[1
]}

机构：

[1] Sogang Univ, Dept Chem & Biomol Engn, 1 Shinsoo Dong, Seoul 121742, South Korea

[2] Chung Ang Univ, Dept Chem, 221 Heukseok Dong, Seoul 156756, South Korea

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2016年 / 34卷

关键词：

Electrolyte; Salting-out effect; Methane solubility; Scale particle theory; Charge density; SCALED-PARTICLE THEORY; METHYLOSINUS-TRICHOSPORIUM OB3B; GAS SOLUBILITY DATA; CARBON-DIOXIDE; SIZE DEPENDENCE; FREE-ENERGIES; WATER; NACL; NONELECTROLYTES; TEMPERATURES;

D O I：

10.1016/j.jiec.2015.10.041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The maximum solubility of methane was determined in aqueous solution of Al-2(SO4)(3), MgSO4, K2SO4, Na2SO4, AlCl3, MgCl2, KCl, NaCl, MgBr2, KBr, and NaBr with various concentration (1, 3 and 5 wt%) at ambient pressure. Salting-out effect was observed in all electrolyte solutions, exhibiting lower solubility of methane compared to that in pure water. In general, electrolyte solutions comprising cations/anions with high charge valency and small ionic radius exhibited stronger salting-out effect due to large charge density of the corresponding ions. Furthermore, anions exhibited larger influence on the degree of salting-out compared to cations. Scaled particle theory was employed to corroborate the trend of the experimental solubility of methane in electrolyte solutions. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：117 / 121

页数：5

共 50 条

[1] Salting-out of methane in the aqueous solutions of urea and sarcosine
Dixit, M. K.
Chatterjee, Anupam
Tembe, B. L.
JOURNAL OF CHEMICAL SCIENCES, 2016, 128 (04) : 599 - 612
[2] Salting-Out of Methane in the Aqueous Solutions of Urea and Glycine-Betaine
Dixit, Mayank Kumar
Siddique, Asrar K.
Tembe, B. L.
JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (34) : 10941 - 10953
[3] Prediction of salting-out and salting-in constants
Marcus, Yizhak
JOURNAL OF MOLECULAR LIQUIDS, 2013, 177 : 7 - 10
[4] Salting-out Effect on the Separation and Purification of Acetic Esters: Salting-out Agents, Theory, and Applications
Xie, Shaoqu
Li, Zhuoxi
Zhu, Guodian
SEPARATION AND PURIFICATION REVIEWS, 2024, 53 (01) : 61 - 81
[5] Density Fluctuation in Aqueous Solutions and Molecular Origin of Salting-Out Effect for CO2
Tuan Anh Ho
Ilgen, Anastasia
JOURNAL OF PHYSICAL CHEMISTRY B, 2017, 121 (51) : 11485 - 11491
[6] Salting-Out Effect in Aqueous NaCl Solutions: Trends with Size and Polarity of Solute Molecules
Endo, Satoshi
Pfennigsdorff, Andrea
Goss, Kai-Uwe
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2012, 46 (03) : 1496 - 1503
[7] Salting-out of some alkyl acetates in aqueous sodium chloride solutions
Segatin, N
Klofutar, C
MONATSHEFTE FUR CHEMIE, 2000, 131 (02): : 131 - 144
[8] Polythermal study of the salting-out of triethylamine from aqueous solutions with sodium nitrate
Cherkasov, D. G.
Il'in, K. K.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (03) : 388 - 394
[9] Salting-out and salting-in effects of amphiphilic salt on cloud point of aqueous methylcellulose
Nishida, Koji
Morita, Hideyuki
Katayama, Yutaka
Inoue, Rintaro
Kanaya, Toshiji
Sadakane, Koichiro
Seto, Hideki
PROCESS BIOCHEMISTRY, 2017, 59 : 52 - 57
[10] The salting-out effect and phase separation in aqueous solutions of sodium phosphate salts and poly(propylene glycol)
Sadeghi, Rahmat
Jamehbozorg, Bahman
FLUID PHASE EQUILIBRIA, 2009, 280 (1-2) : 68 - 75

← 1 2 3 4 5 →