Nickel N-Heterocyclic Carbene Catalyst for Cross-Coupling of Neopentyl Arenesulfonates with Methyl and Primary Alkyl Grignard Reagents

被引：31

作者：

Kim, Chul-Bae ^{[1
]}

Jo, Hyunjong ^{[1
]}

Ahn, Bo-Kyoung ^{[1
]}

Kim, Chang Keun ^{[1
]}

Park, Kwangyong ^{[1
]}

机构：

[1] Chung Ang Univ, Sch Chem Engn & Mat Sci, Seoul 156756, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 24期

关键词：

UNACTIVATED ARYL CHLORIDES; C BOND FORMATION; ROOM-TEMPERATURE; NHC LIGANDS; RESTRICTED FLEXIBILITY; ARYLBORONIC ACIDS; COMPLEXES; AMINATION; BROMIDES; HALIDES;

D O I：

10.1021/jo902151h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickel N-heterocyclic carbene (NHC) catalytic system prepared in Situ by the reaction of Ni(acac)(2) with NHC precursor efficiently catalyzed the cross-coupling reaction of alkoxysulfonylarenes with methyl, neopentyl, and benzyl Grignard reagents at ambient temperature.

引用

页码：9566 / 9569

页数：4

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