Supramolecular Assemblies of Dipyrrolyldiketone CuII Complexes

被引：3

作者：

Haketa, Yohei ^{[1
]}

Maeda, Hiromitsu ^{[1
]}

机构：

[1] Ritsumeikan Univ, Dept Appl Chem, Coll Life Sci, Kusatsu 5258577, Japan

来源：

MOLECULES | 2021年 / 26卷 / 04期

关键词：

π -electronic systems; dipyrrolyldiketones; Cu-II complexes; crystal structures; mesophases; ANION RECEPTORS; SUBSTITUTED DIPYRROLYLDIKETONES; INTERMOLECULAR INTERACTIONS; BUILDING-BLOCKS; BF2; COMPLEXES; METALLOMESOGENS; COPPER(II); MODULES; SERIES;

D O I：

10.3390/molecules26040861

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Dipyrrolyldiketones are essential building units of anion-responsive pi-electronic molecules and ion-pairing assemblies. Here, we demonstrated that they form complexes with Cu-II characterized by planar geometries. The solid-state stacking assembled structures, as revealed by single-crystal X-ray analysis, were modulated by the substitution of pyrrole units. The rectangular shapes of the Cu-II complexes resulted in the formation of mesophases upon introduction of aliphatic chains.

引用

页数：13

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