Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates

被引:13
作者
Duong, Hung A. [1 ]
Yeow, Zong-Han [1 ]
Tiong, Yong-Lun [1 ]
Kamal, Nur Haidah Binte Mohamad [1 ]
Wu, Wenqin [1 ]
机构
[1] ASTAR, ICES, 8 Biomed Grove,Neuros 07-01, Singapore 138665, Singapore
关键词
PALLADIUM; ALKYL; HALIDES; TRANSMETALATION; ARYLATION; CHLORIDES; REAGENTS; COMPLEX;
D O I
10.1021/acs.joc.9b02105
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A catalyst system comprising CoCl2/IAd center dot HBF4 enables the Suzuki-Miyaura cross-coupling reaction of a broad range of aryl triflates and arylboronic esters that are activated by n-butyllithium.
引用
收藏
页码:12686 / 12691
页数:6
相关论文
共 43 条
  • [1] [Anonymous], 2008, ORGANOMETALLICS
  • [2] Cobalt-Catalyzed Suzuki Biaryl Coupling of Aryl Halides
    Asghar, Soneela
    Tailor, Sanita B.
    Elorriaga, David
    Bedford, Robin B.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (51) : 16367 - 16370
  • [3] Iron Catalysis in Organic Synthesis
    Bauer, Ingmar
    Knoelker, Hans-Joachim
    [J]. CHEMICAL REVIEWS, 2015, 115 (09) : 3170 - 3387
  • [4] Expedient Iron-Catalyzed Coupling of Alkyl, Benzyl and Allyl Halides with Arylboronic Esters
    Bedford, Robin B.
    Brenner, Peter B.
    Carter, Emma
    Carvell, Thomas W.
    Cogswell, Paul M.
    Gallagher, Timothy
    Harvey, Jeremy N.
    Murphy, Damien M.
    Neeve, Emily C.
    Nunn, Joshua
    Pye, Dominic R.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (26) : 7935 - 7938
  • [5] Simple mixed Fe-Zn catalysts for the Suzuki couplings of tetraarylborates with benzyl halides and 2-halopyridines
    Bedford, Robin B.
    Hall, Mark A.
    Hodges, George R.
    Huwe, Michael
    Wilkinson, Mark C.
    [J]. CHEMICAL COMMUNICATIONS, 2009, (42) : 6430 - 6432
  • [6] Iron-Catalyzed C-O Bond Activation: Opportunity for Sustainable Catalysis
    Bisz, Elwira
    Szostak, Michal
    [J]. CHEMSUSCHEM, 2017, 10 (20) : 3964 - 3981
  • [7] Cobalt-Catalyzed Cross-Coupling Reactions
    Cahiez, Gerard
    Moyeux, Alban
    [J]. CHEMICAL REVIEWS, 2010, 110 (03) : 1435 - 1462
  • [8] Iron(II) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates
    Chua, Yi-Yuan
    Duong, Hung A.
    [J]. CHEMICAL COMMUNICATIONS, 2016, 52 (07) : 1466 - 1469
  • [9] Selective Kumada biaryl cross-coupling reaction enabled by an iron(III) alkoxide-N-heterocyclic carbene catalyst system
    Chua, Yi-Yuan
    Duong, Hung A.
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (61) : 8424 - 8427
  • [10] Key green chemistry research areas - a perspective from pharmaceutical manufacturers
    Constable, David J. C.
    Dunn, Peter J.
    Hayler, John D.
    Humphrey, Guy R.
    Leazer, Johnnie L., Jr.
    Linderman, Russell J.
    Lorenz, Kurt
    Manley, Julie
    Pearlman, Bruce A.
    Wells, Andrew
    Zaks, Aleksey
    Zhang, Tony Y.
    [J]. GREEN CHEMISTRY, 2007, 9 (05) : 411 - 420