An efficient reduction of N-substituted carbonylimidazolides into formamides by NaBH4

被引：6

作者：

Chen, Zhiyong ^{[1
]}

Cao, Yiming ^{[1
]}

Tian, Zeyu ^{[1
]}

Zhou, Xuan ^{[1
]}

Xu, Wenjin ^{[1
]}

Yang, Jia ^{[1
]}

Teng, Hanbing ^{[1
]}

机构：

[1] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, 122 Luoshi Rd, Wuhan 430070, Peoples R China

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 22期

关键词：

N-Substituted carbonylimidazolide; Formamide; Reduction; Sodium borohydride; AMINO-ACIDS/PEPTIDE-ACIDS; RETRO-INVERSO PEPTIDES; ASYMMETRIC ALLYLATION; EMPLOYING ISOCYANATES; ONE-POT; CARBAMOYLIMIDAZOLE; ORGANOCATALYSIS; ISOCYANIDES; DERIVATIVES; SULFIDE;

D O I：

10.1016/j.tetlet.2017.04.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel, simple and versatile protocol was investigated for highly efficient synthesis of formamides through reducing N-substituted carbonylimidazolides by NaBH4 under mild reaction conditions. By this method, not only carboxylic acids or isocyanates, but also amines can readily access formamides with high yields. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：2166 / 2170

页数：5

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