Synthesis of submicron size hollow carbon spheres by a chemical reduction - solvothermal method using carbon tetrachloride as carbon source

被引：31

作者：

Sawant, Sandesh Y. ^{[1
]}

Somani, Rajesh S. ^{[1
]}

Newalkar, Bharat L. ^{[2
]}

Choudary, Nettem V. ^{[2
]}

Bajaj, Hari C. ^{[1
]}

机构：

[1] CSIR, Cent Salt & Marine Chem Res Inst, Discipline Inorgan Mat & Catalysis, Bhavnagar 364002, Gujarat, India

[2] Bharat Petr Corp Ltd, Corp R&D Ctr, Greater Noida 201306, India

来源：

MATERIALS LETTERS | 2009年 / 63卷 / 27期

关键词：

Submicron carbon spheres; Carbon tetrachloride; Chemical reduction; Solvothermal method; ROUTE; NANOSPHERES; NANOTUBES;

D O I：

10.1016/j.matlet.2009.07.066

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple, rapid and energy efficient approach based on copper mediated chemical reduction - solvothermal method was employed to prepare submicron size hollow carbon spheres (SHCS) using carbon tetrachloride as carbon source. The obtained SHCS were characterized by means of various physico-chemical techniques like nitrogen adsorption-desorption measurements at 77 K, XRD, SEM, TEM, EDX and Fr-Raman techniques. Thus characterized samples displayed macroporous nature of carbon with carbon and chloride contents of about 73% and 12% on atomic basis respectively. The presence of chloride content may open new avenues for surface modifications of SHCS in the area of catalysis and separation science. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2339 / 2342

页数：4

共 24 条

[11] Carbon nanopipettes [J].

Mani, RC ;

Li, X ;

Sunkara, MK ;

Rajan, K .

NANO LETTERS, 2003, 3 (05) :671-673

[12] Synthesis of carbon micro-spheres by a glucose hydrothermal method [J].

Mi, Yuanzhu ;

Hu, Weibing ;

Dan, Youmeng ;

Liu, Yingliang .

MATERIALS LETTERS, 2008, 62 (8-9) :1194-1196

[13] Carbon nanospheres produced in an arc-discharge process [J].

Qiao, WM ;

Song, Y ;

Lim, SY ;

Hong, SH ;

Yoon, SH ;

Mochida, I ;

Imaoka, T .

CARBON, 2006, 44 (01) :187-190

[14] A novel form of carbon micro-balls from coal [J].

Qiu, HS ;

Li, YF ;

Wang, YP ;

Liang, CH ;

Wang, TH ;

Wang, D .

CARBON, 2003, 41 (04) :767-772

[15] CARBON NANOFIBERS - A UNIQUE CATALYST SUPPORT MEDIUM [J].

RODRIGUEZ, NM ;

KIM, MS ;

BAKER, RTK .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (50) :13108-13111

[16]

Ryoo R, 2001, ADV MATER, V13, P677, DOI 10.1002/1521-4095(200105)13:9<677::AID-ADMA677>3.3.CO

[17]

2-3

[18] Synthesis and characterization of carbon spheres prepared by chemical vapour deposition [J].

Wang, Peng ;

Wei, Jiyong ;

Huang, Baibiao ;

Qin, Xiaoyan ;

Yao, Shushan ;

Zhang, Qi ;

Wang, Zeyan ;

Xu, Guanghui ;

Jing, Xiangyang .

MATERIALS LETTERS, 2007, 61 (26) :4854-4856

[19] A novel approach to carbon hollow spheres and vessels from CCl4 at low temperatures [J].

Xiong, YJ ;

Xie, Y ;

Li, ZQ ;

Wu, CZ ;

Zhang, R .

CHEMICAL COMMUNICATIONS, 2003, (07) :904-905

[20] A novel route to hollow and solid carbon spheres [J].

Xu, LQ ;

Zhang, WQ ;

Yang, Q ;

Ding, YW ;

Yu, WC ;

Qian, YT .

CARBON, 2005, 43 (05) :1090-1092

← 1 2 3 →