Novel and efficient synthesis of perfluoroalkylated arylphosphines

被引：33
作者：
Chen, WP [1 ]
Xiao, JL [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 19期
基金：
英国工程与自然科学研究理事会;
关键词：
perfluoroalkylated phosphines; copper-mediated coupling; arylphosphines;
D O I：
10.1016/S0040-4039(00)00445-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel, high-yield route has been developed for the synthesis of perfluoroalkylated arylphosphines, involving simple, copper-mediated coupling of haloarylphosphine oxides with perfluoroalkyl iodides followed by reduction with trichlorosilane. (C) 2000 Elsevier Science Ltd. All rights reserved.
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收藏
页码：3697 / 3700
页数：4
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