Efficient purification of arsenic-contaminated water using amyloid-carbon hybrid membranes

被引:76
作者
Bolisetty, Sreenath [1 ]
Reinhold, Noemi [1 ]
Zeder, Christophe [1 ]
Orozco, Monica N. [2 ]
Mezzenga, Raffaele [1 ,3 ]
机构
[1] ETH, Dept Hlth Sci & Technol, Schmelzbergstr 9, CH-8092 Zurich, Switzerland
[2] Univ Valle Guatemala, Ctr Estudios Atitlan, Campus Altiplano,Km 137 Caserio Xolbe, Canton El Tablon, Solola, Guatemala
[3] ETH, Dept Mat, Wolfgang Pauli Str 10, CH-8093 Zurich, Switzerland
关键词
REMOVAL; REMEDIATION; AGGREGATION; OXIDATION; BINDING; HAZARDS;
D O I
10.1039/c7cc00406k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We show the purification of arsenic-contaminated water using amyloid fibril-based membranes, which adsorb both the arsenate (+5) and arsenite (+3) oxidation forms at efficiencies of similar to 99%. Binding isotherms indicate that amyloid fibrils possess multiple binding residues capable of strongly adsorbing arsenic ions via metal-ligand interactions, delaying the saturation of the membrane. We also show that these membranes can be reused for several cycles without any efficiency drop, and validate our technology in purifying real contaminated ground water by removing arsenic with an efficiency as high as 99.6%. These results make this technology promising for inexpensive, efficient and lowenergy removal of arsenic from contaminated water.
引用
收藏
页码:5714 / 5717
页数:4
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