catena-Poly[[[[3-(2-pyridyl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]

被引:1
作者
An, Zhe [1 ]
Zhu, Ling [1 ]
机构
[1] Maoming Univ, Sch Chem & Life Sci, Maoming 525000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536809044298
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, {[Mn(C2O4)(C8H7N3)]center dot 1.5H(2)O}(n), the Mn-II ion is chelated by two O,O'-bidentate oxalate ions and an N,N'-bidentate 3-(2-pyridyl)pyrazole molecule, resulting in a distorted cis-MnN2O4 octahedral geometry for the metal ion. The bridging oxalate ions generate wave-like polymeric chains propagating in [001]. The packing is consolidated by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds. One of the water O atoms lies on a crystallographic twofold axis.
引用
收藏
页码:M1480 / U2131
页数:10
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