Solar-Energy-Mediated Methane Conversion

被引：336

作者：

Song, Hui ^{[1
,3
]}

Meng, Xianguang ^{[1
,4
]}

Wang, Zhou-jun ^{[1
,2
]}

Liu, Huimin ^{[1
,5
,6
]}

Ye, Jinhua ^{[1
,3
,6
,7
]}

机构：

[1] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan

[2] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Energy Environm Catalysis, 15 Beisanhuan East Rd, Beijing 100029, Peoples R China

[3] Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0600814, Japan

[4] North China Univ Sci & Technol, Coll Mat Sci & Engn, Hebei Prov Key Lab Nonmetall Mat, Tangshan 063210, Peoples R China

[5] Univ Sydney, Sch Chem & Biomol Engn, Chem Engn Bldg J01, Sydney, NSW 2006, Australia

[6] Tianjin Univ, Sch Mat Sci & Engn, TJU NIMS Int Collaborat Lab, Tianjin 300072, Peoples R China

[7] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

JOULE | 2019年 / 3卷 / 07期

基金：

中国国家自然科学基金;

关键词：

C-H BOND; SUPPORTED ZIRCONIUM-OXIDE; ASSISTED CO2 REDUCTION; PHOTOCATALYTIC CONVERSION; ROOM-TEMPERATURE; CARBON-DIOXIDE; CATALYTIC CONVERSION; PARTIAL OXIDATION; GALLIUM OXIDE; SELECTIVE OXIDATION;

D O I：

10.1016/j.joule.2019.06.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conversion of methane to upgraded fuels and higher-value chemicals such as hydrogen, methanol, and olefins is a promising technology in the supply of chemicals and energy. However, current commercial methane conversion technology suffers from intense energy consumption. It is highly desirable to develop novel technologies for methane conversion with improved efficiency and lower cost. Solar energy, the most abundant and clean renewable energy, has been utilized as a new stimulus to drive methane conversion under mild conditions. In this review, recent achievements in solar-energy-mediated catalytic methane conversion are highlighted. We focus on the photocatalytic conversion of methane in photocatalytic systems, photoelectrochemical systems, and photoenhanced thermocatalytic systems. We discuss the challenges and prospects of future research on solar-energy-mediated methane conversion and aim to acquire in-depth understanding of the photo-mediated activation of the C-H bond and provide guidelines for the design of highly efficient catalysts.

引用

页码：1606 / 1636

页数：31

共 146 条

[51] REACTIONS OF METHANE AND ETHANE WITH HOLE-CENTERS O [J].