Novel thermal reaction of Fischer carbene complexes with imines:: Synthesis of β-methoxy allylic amine derivatives

被引：5

作者：

Sangu, K ^{[1
]}

Kagoshima, H ^{[1
]}

Fuchibe, K ^{[1
]}

Akiyama, T ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 22期

关键词：

D O I：

10.1021/ol026852g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Alkyl-substituted chromium Fischer carbene complexes were found to react with various N-tosylimines to give,beta-methoxy allylic amine derivatives under thermal conditions. This result is essentially distinct from the photochemical outcome in which beta-lactam derivatives are obtained.

引用

页码：3967 / 3969

页数：3

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