Intercalation of tetraazamacrocycles into molybdenum disulfide

被引：32

作者：

Bissessur, R ^{[1
]}

Haines, RI

Brüning, R

机构：

[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[2] Mt Allison Univ, Dept Phys, Sackville, NB E4L 1E6, Canada

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 01期

关键词：

D O I：

10.1039/b208237n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the intercalated macrocycles are co-planar with the MoS2 sheets.

引用

页码：44 / 49

页数：6

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