Intercalation of tetraazamacrocycles into molybdenum disulfide

被引：32
作者：
Bissessur, R [1 ]
Haines, RI
Brüning, R
机构：
[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada
[2] Mt Allison Univ, Dept Phys, Sackville, NB E4L 1E6, Canada
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 01期
关键词：
D O I：
10.1039/b208237n
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the intercalated macrocycles are co-planar with the MoS2 sheets.
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页码：44 / 49
页数：6
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